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Hybrid macromolecular iron and copper complexes in the phenol hydroxylation reaction

Karakhanov, E. A. / Maksimov, A. L. / Zatolochnaya, O. V. / Rosenberg, E. / Hughes, M. / Kailasam, P.

Abstract Macromolecular iron and copper complexes based on hybrid materials with grafted polyamine polymers have been synthesized. It has been shown that the silica gel-immobilized iron complexes with polyallylamine-supported EDTA and copper complexes with polyethyleneimine exhibit a high activity in phenol hydroxylation with hydrogen peroxide. The catalysts can be recycled without the loss of activity.

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Hybrid macromolecular iron and copper complexes in the phenol hydroxylation reaction

Karakhanov, E. A. / Maksimov, A. L. / Zatolochnaya, O. V. / Rosenberg, E. / Hughes, M. / Kailasam, P.

Abstract Macromolecular iron and copper complexes based on hybrid materials with grafted polyamine polymers have been synthesized. It has been shown that the silica gel-immobilized iron complexes with polyallylamine-supported EDTA and copper complexes with polyethyleneimine exhibit a high activity in phenol hydroxylation with hydrogen peroxide. The catalysts can be recycled without the loss of activity.

Hybrid macromolecular iron and copper complexes in the phenol hydroxylation reaction

Karakhanov, E. A. / Maksimov, A. L. / Zatolochnaya, O. V. / Rosenberg, E. / Hughes, M. / Kailasam, P.

Abstract Macromolecular iron and copper complexes based on hybrid materials with grafted polyamine polymers have been synthesized. It has been shown that the silica gel-immobilized iron complexes with polyallylamine-supported EDTA and copper complexes with polyethyleneimine exhibit a high activity in phenol hydroxylation with hydrogen peroxide. The catalysts can be recycled without the loss of activity.

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Title:

Hybrid macromolecular iron and copper complexes in the phenol hydroxylation reaction

Contributors:

Karakhanov, E. A. (author) / Maksimov, A. L. (author) / Zatolochnaya, O. V. (author) / Rosenberg, E. (author) / Hughes, M. (author) / Kailasam, P. (author)

Published in:

Petroleum Chemistry ; 49 ; 107-113

Publication date:

2009-03-01

Size:

7 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544109020017

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Hybrid Material , Copper Complex , Petroleum Chemistry , Phenol Hydroxylation , Pyrocatechol Chemistry , Industrial Chemistry/Chemical Engineering

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