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Cometathesis of cyclopentene with α-olefins on the MoCl5/SiO2-SnMe4 catalyst system
Abstract The stereoisomeric composition of 1,6-dienes as the main (70–80%) desired products of cyclopentene comethathesis with hexene-1 and octene-1 and symmetric olefins (decene-5 and tetradecene-7) that are the products of hexene-1 metathesis with octene-1 were studied depending on the conversion of cyclopentene at different temperatures and reaction conditions (hexene-1: cyclopentene molar ratio, presence of triphenylphosphine additives) over the MoCl5/SiO2-SnMe4 catalyst system. It was shown that, at cyclopentene conversions of 1–55%, the amount of thermodynamically less favorable 1,Z-6-undecadiene and 1,Z-6-tridecadiene was 80–50%, whereas the amount of the metathesis products Z-decene-5 and tetradecene-7 was 25–16%. The stereoisomeric composition of 1,6-undecadiene and 1,6-tridecadiene tends to the thermodynamically equilibrium composition (Z/E = 16: 84) with an increase in the cyclopentene conversion and reaches this composition at the equilibrium conversion of cyclopentene (77%, 25°C). The chemical and stereomeric compositions of the cometathesis products are independent of the length of the α-olefin carbon chain.
Cometathesis of cyclopentene with α-olefins on the MoCl5/SiO2-SnMe4 catalyst system
Abstract The stereoisomeric composition of 1,6-dienes as the main (70–80%) desired products of cyclopentene comethathesis with hexene-1 and octene-1 and symmetric olefins (decene-5 and tetradecene-7) that are the products of hexene-1 metathesis with octene-1 were studied depending on the conversion of cyclopentene at different temperatures and reaction conditions (hexene-1: cyclopentene molar ratio, presence of triphenylphosphine additives) over the MoCl5/SiO2-SnMe4 catalyst system. It was shown that, at cyclopentene conversions of 1–55%, the amount of thermodynamically less favorable 1,Z-6-undecadiene and 1,Z-6-tridecadiene was 80–50%, whereas the amount of the metathesis products Z-decene-5 and tetradecene-7 was 25–16%. The stereoisomeric composition of 1,6-undecadiene and 1,6-tridecadiene tends to the thermodynamically equilibrium composition (Z/E = 16: 84) with an increase in the cyclopentene conversion and reaches this composition at the equilibrium conversion of cyclopentene (77%, 25°C). The chemical and stereomeric compositions of the cometathesis products are independent of the length of the α-olefin carbon chain.
Cometathesis of cyclopentene with α-olefins on the MoCl5/SiO2-SnMe4 catalyst system
Bykov, V. I. (author) / Red’kin, D. V. (author) / Kelbakiani, L. V. (author) / Butenko, T. A. (author) / Finkel’shtein, E. Sh. (author)
Petroleum Chemistry ; 46 ; 113-116
2006-03-01
4 pages
Article (Journal)
Electronic Resource
English
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