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Interaction of 2-Monosubstituted 1,3-Dioxolanes with Aluminacyclopentanes

Dekhtyar’, T. F. / Vostrikova, O. S. / Zlotskii, S. S. / Bogomazova, A. A. / Mikhailova, N. N.

Abstract The interaction of 2-monosubstituted 1,3-dioxolanes with 3-hexyl-1-ethylaluminacyclopentane leads to the cleavage of the Al–C bond of the metallocycle and the formation of ethylene glycol monoethers after hydrolysis of the resulting reaction mixture. Catalytic amounts of ZrCl4 or Ni(acac)2 activate the process. The reaction of 2-monosubstituted 1,3-dioxolanes with 1-ethyl-3-naphthylaluminacyclopentane yields the product of cleavage of the exocyclic Al–Et bond of aluminacyclopentane.

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Interaction of 2-Monosubstituted 1,3-Dioxolanes with Aluminacyclopentanes

Dekhtyar’, T. F. / Vostrikova, O. S. / Zlotskii, S. S. / Bogomazova, A. A. / Mikhailova, N. N.

Abstract The interaction of 2-monosubstituted 1,3-dioxolanes with 3-hexyl-1-ethylaluminacyclopentane leads to the cleavage of the Al–C bond of the metallocycle and the formation of ethylene glycol monoethers after hydrolysis of the resulting reaction mixture. Catalytic amounts of ZrCl4 or Ni(acac)2 activate the process. The reaction of 2-monosubstituted 1,3-dioxolanes with 1-ethyl-3-naphthylaluminacyclopentane yields the product of cleavage of the exocyclic Al–Et bond of aluminacyclopentane.

Interaction of 2-Monosubstituted 1,3-Dioxolanes with Aluminacyclopentanes

Dekhtyar’, T. F. / Vostrikova, O. S. / Zlotskii, S. S. / Bogomazova, A. A. / Mikhailova, N. N.

Abstract The interaction of 2-monosubstituted 1,3-dioxolanes with 3-hexyl-1-ethylaluminacyclopentane leads to the cleavage of the Al–C bond of the metallocycle and the formation of ethylene glycol monoethers after hydrolysis of the resulting reaction mixture. Catalytic amounts of ZrCl4 or Ni(acac)2 activate the process. The reaction of 2-monosubstituted 1,3-dioxolanes with 1-ethyl-3-naphthylaluminacyclopentane yields the product of cleavage of the exocyclic Al–Et bond of aluminacyclopentane.

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Title:

Interaction of 2-Monosubstituted 1,3-Dioxolanes with Aluminacyclopentanes

Contributors:

Dekhtyar’, T. F. (author) / Vostrikova, O. S. (author) / Zlotskii, S. S. (author) / Bogomazova, A. A. (author) / Mikhailova, N. N. (author)

Published in:

Petroleum Chemistry ; 59 ; 650-655

Publication date:

2019-06-01

Size:

6 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544119060082

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

organoaluminum compounds , aluminacyclopentanes , 1,3-dioxolane , catalysis , zirconium tetrachloride Chemistry , Industrial Chemistry/Chemical Engineering

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