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Synthesis and Characterization of a Water Soluble PPV Derivative

Shi, Songqing / Wudl, Fred

Abstract A water soluble poly (p-phenylenevinylene) (PPV) precursor polymer was prepared in eight steps from p-methoxyphenol. The precursor polymer was of very high molecular weight (ca. 106 Daltons) and was converted to the conjugated polymer both in solution and in the solid state. The latter method produces a crosslinked material which is insoluble in all common solvents and water. The former method affords a water soluble PPV. Some physical and chemical properties such as in situ spectroscopy and conductivity measurements are presented.

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Synthesis and Characterization of a Water Soluble PPV Derivative

Shi, Songqing / Wudl, Fred

Abstract A water soluble poly (p-phenylenevinylene) (PPV) precursor polymer was prepared in eight steps from p-methoxyphenol. The precursor polymer was of very high molecular weight (ca. 106 Daltons) and was converted to the conjugated polymer both in solution and in the solid state. The latter method produces a crosslinked material which is insoluble in all common solvents and water. The former method affords a water soluble PPV. Some physical and chemical properties such as in situ spectroscopy and conductivity measurements are presented.

Synthesis and Characterization of a Water Soluble PPV Derivative

Shi, Songqing / Wudl, Fred

Abstract A water soluble poly (p-phenylenevinylene) (PPV) precursor polymer was prepared in eight steps from p-methoxyphenol. The precursor polymer was of very high molecular weight (ca. 106 Daltons) and was converted to the conjugated polymer both in solution and in the solid state. The latter method produces a crosslinked material which is insoluble in all common solvents and water. The former method affords a water soluble PPV. Some physical and chemical properties such as in situ spectroscopy and conductivity measurements are presented.

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Title:

Synthesis and Characterization of a Water Soluble PPV Derivative

Contributors:

Shi, Songqing (author) / Wudl, Fred (author)

Published in:

Conjugated Polymeric Materials: Opportunities in Electronics, Optoelectronics, and Molecular Electronics ; 83-89

NATO ASI Series ; 182

Publication date:

1990-01-01

Size:

7 pages

ISBN:

978-94-010-7416-2 , 978-94-009-2041-5

ISSN:

DOI:

https://doi.org/10.1007/978-94-009-2041-5_5

Type of media:

Article/Chapter (Book)

Type of material:

Electronic Resource

Language:

English

Keywords:

Sodium Methoxide , Precursor Polymer , Methanesulfonic Acid , Ammonia Vapor , Trifluoromethanesulfonic Acid Chemistry , Industrial Chemistry/Chemical Engineering , Characterization and Evaluation of Materials , Organic Chemistry , Optics, Lasers, Photonics, Optical Devices

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