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Cation-exchange resins in the hydroformylation–acetalization tandem reaction
Abstract Cation-exchange resins in the acid form (Amberlyst-16, Wofatit KPS 200, Nafion, KU-2) have been tested as the acidic component of a catalyst system for the hydroformylation–acetalization tandem process. It has been shown that the hydroformylation of octene-1 in the presence of ethylene glycol and glycerol using a catalyst system comprising a rhodium complex, a phosphine ligand, and a solid acid leads to the formation of acetals with a yield of up to 99%.
Cation-exchange resins in the hydroformylation–acetalization tandem reaction
Abstract Cation-exchange resins in the acid form (Amberlyst-16, Wofatit KPS 200, Nafion, KU-2) have been tested as the acidic component of a catalyst system for the hydroformylation–acetalization tandem process. It has been shown that the hydroformylation of octene-1 in the presence of ethylene glycol and glycerol using a catalyst system comprising a rhodium complex, a phosphine ligand, and a solid acid leads to the formation of acetals with a yield of up to 99%.
Cation-exchange resins in the hydroformylation–acetalization tandem reaction
Gorbunov, D. N. (author) / Shchukina, T. V. (author) / Kardasheva, Yu. S. (author) / Sinikova, N. A. (author) / Maksimov, A. L. (author) / Karakhanov, E. A. (author)
Petroleum Chemistry ; 56 ; 711-716
2016-08-01
6 pages
Article (Journal)
Electronic Resource
English
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