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    Nanoheterogeneous ruthenium-containing catalysts based on dendrimers in the hydrogenation of aromatic compounds under two-phase conditions

    New search for: Karakhanov, E. A.
    New search for: Maximov, A. L.
    New search for: Zolotukhina, A. V.
    New search for: Terenina, M. V.
    New search for: Vutolkina, A. V.

    Abstract Nanoheterogeneous catalysts based on ruthenium nanoparticles dispersed in crosslinked dendrimer matrixes with a size of polymer particles of 100–500 nm show high activity in the hydrogenation of aromatic compounds under two-phase conditions. The addition of water to the reaction medium exerts a strong promoting effect on the activity of the catalysts: The turnover frequency increases by a factor of 3–90 depending on the substrate. When bimetallic (PdRu) nanoparticles are incorporated into the catalyst composition, the rate of benzene hydrogenation increases while the rate of transformation of substituted benzenes decreases.

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    Nanoheterogeneous ruthenium-containing catalysts based on dendrimers in the hydrogenation of aromatic compounds under two-phase conditions

    New search for: Karakhanov, E. A.
    New search for: Maximov, A. L.
    New search for: Zolotukhina, A. V.
    New search for: Terenina, M. V.
    New search for: Vutolkina, A. V.

    Abstract Nanoheterogeneous catalysts based on ruthenium nanoparticles dispersed in crosslinked dendrimer matrixes with a size of polymer particles of 100–500 nm show high activity in the hydrogenation of aromatic compounds under two-phase conditions. The addition of water to the reaction medium exerts a strong promoting effect on the activity of the catalysts: The turnover frequency increases by a factor of 3–90 depending on the substrate. When bimetallic (PdRu) nanoparticles are incorporated into the catalyst composition, the rate of benzene hydrogenation increases while the rate of transformation of substituted benzenes decreases.

    Access

    Check access
    Check availability in my library
    Order at Subito €

    Nanoheterogeneous ruthenium-containing catalysts based on dendrimers in the hydrogenation of aromatic compounds under two-phase conditions

    New search for: Karakhanov, E. A.
    New search for: Maximov, A. L.
    New search for: Zolotukhina, A. V.
    New search for: Terenina, M. V.
    New search for: Vutolkina, A. V.

    Abstract Nanoheterogeneous catalysts based on ruthenium nanoparticles dispersed in crosslinked dendrimer matrixes with a size of polymer particles of 100–500 nm show high activity in the hydrogenation of aromatic compounds under two-phase conditions. The addition of water to the reaction medium exerts a strong promoting effect on the activity of the catalysts: The turnover frequency increases by a factor of 3–90 depending on the substrate. When bimetallic (PdRu) nanoparticles are incorporated into the catalyst composition, the rate of benzene hydrogenation increases while the rate of transformation of substituted benzenes decreases.

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    Title:

    Nanoheterogeneous ruthenium-containing catalysts based on dendrimers in the hydrogenation of aromatic compounds under two-phase conditions

    Contributors:

    Karakhanov, E. A. (author) / Maximov, A. L. (author) / Zolotukhina, A. V. (author) / Terenina, M. V. (author) / Vutolkina, A. V. (author)

    Published in:

    Petroleum Chemistry ; 56 ; 491-502

    Publication date:

    2016-06-01

    Size:

    12 pages

    ISSN:

    1555-6239 , 0965-5441

    DOI:

    https://doi.org/10.1134/S0965544116060037

    Type of media:

    Article (Journal)

    Type of material:

    Electronic Resource

    Language:

    English

    Keywords:

    catalytic hydrogenation , aromatic compounds , two-phase catalysis , bimetallic nanoparticles , dendrimers , ruthenium , palladium Chemistry , Industrial Chemistry/Chemical Engineering

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