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Deactivation features of gallium-containing zeolites in the propane aromatization process

Vosmerikova, L. N. / Zaikovskii, V. I. / Volynkina, A. N. / Vosmerikov, A. V.

Abstract Conversion of propane to aromatic hydrocarbons on Ga-containing zeolite catalysts prepared by various methods has been examined, and their comparative stability against deactivation has been analyzed. It has been shown that the Ga-containing zeolite catalysts exhibit high activity and stability in propane conversion to aromatic hydrocarbons. Specific features of the formation of carbon deposits on the surface of Ga-containing zeolites in the propane aromatization reaction have been revealed using the techniques of temperature-programmed desorption of ammonia, low-temperature adsorption of nitrogen, differential thermal analysis, high-resolution transmission electron microscopy, and characteristic X-ray spectroscopy radiation. It has been found that the coke deposited on the catalyst has an almost homogeneous structure and is characterized by relatively low degree of polycondensation.

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Deactivation features of gallium-containing zeolites in the propane aromatization process

Vosmerikova, L. N. / Zaikovskii, V. I. / Volynkina, A. N. / Vosmerikov, A. V.

Abstract Conversion of propane to aromatic hydrocarbons on Ga-containing zeolite catalysts prepared by various methods has been examined, and their comparative stability against deactivation has been analyzed. It has been shown that the Ga-containing zeolite catalysts exhibit high activity and stability in propane conversion to aromatic hydrocarbons. Specific features of the formation of carbon deposits on the surface of Ga-containing zeolites in the propane aromatization reaction have been revealed using the techniques of temperature-programmed desorption of ammonia, low-temperature adsorption of nitrogen, differential thermal analysis, high-resolution transmission electron microscopy, and characteristic X-ray spectroscopy radiation. It has been found that the coke deposited on the catalyst has an almost homogeneous structure and is characterized by relatively low degree of polycondensation.

Deactivation features of gallium-containing zeolites in the propane aromatization process

Vosmerikova, L. N. / Zaikovskii, V. I. / Volynkina, A. N. / Vosmerikov, A. V.

Abstract Conversion of propane to aromatic hydrocarbons on Ga-containing zeolite catalysts prepared by various methods has been examined, and their comparative stability against deactivation has been analyzed. It has been shown that the Ga-containing zeolite catalysts exhibit high activity and stability in propane conversion to aromatic hydrocarbons. Specific features of the formation of carbon deposits on the surface of Ga-containing zeolites in the propane aromatization reaction have been revealed using the techniques of temperature-programmed desorption of ammonia, low-temperature adsorption of nitrogen, differential thermal analysis, high-resolution transmission electron microscopy, and characteristic X-ray spectroscopy radiation. It has been found that the coke deposited on the catalyst has an almost homogeneous structure and is characterized by relatively low degree of polycondensation.

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Title:

Deactivation features of gallium-containing zeolites in the propane aromatization process

Contributors:

Vosmerikova, L. N. (author) / Zaikovskii, V. I. (author) / Volynkina, A. N. (author) / Vosmerikov, A. V. (author)

Published in:

Petroleum Chemistry ; 57 ; 85-92

Publication date:

2017-01-01

Size:

8 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544116090231

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

propane , aromatic hydrocarbons , zeolite , conversion , activity , selectivity , coke , carbon deposits Chemistry , Industrial Chemistry/Chemical Engineering

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