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Zeolite catalysts modified with zirconium and sulfur compounds in the conversion of dimethyl ether to lower olefins
Abstract The effect of zirconium addition to zeolite-containing catalysts for dimethyl ether conversion to lower olefins has been studied. The effect of the nature of the zirconium compound on the catalytic properties of a zeolite catalyst has been analyzed, and a method for generating new acid sites through the sulfation of a Zr-containing zeolite matrix has been developed. Using physicochemical methods, it has been shown that the processing of a zeolite with zirconium and sulfur compounds does not lead to the degradation of its structure and a change in the adsorption volume.
Zeolite catalysts modified with zirconium and sulfur compounds in the conversion of dimethyl ether to lower olefins
Abstract The effect of zirconium addition to zeolite-containing catalysts for dimethyl ether conversion to lower olefins has been studied. The effect of the nature of the zirconium compound on the catalytic properties of a zeolite catalyst has been analyzed, and a method for generating new acid sites through the sulfation of a Zr-containing zeolite matrix has been developed. Using physicochemical methods, it has been shown that the processing of a zeolite with zirconium and sulfur compounds does not lead to the degradation of its structure and a change in the adsorption volume.
Zeolite catalysts modified with zirconium and sulfur compounds in the conversion of dimethyl ether to lower olefins
Kolesnichenko, N. V. (author) / Kolesnikova, E. E. (author) / Kitaev, L. E. (author) / Biryukova, E. N. (author) / Trukhmanova, N. I. (author) / Khadzhiev, S. N. (author)
Petroleum Chemistry ; 52 ; 155-160
2012-05-01
6 pages
Article (Journal)
Electronic Resource
English
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