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Kinetics and mechanism of the catalytic reaction of ozone with toluene in the liquid phase

Galstyan, S. G. / Tyupalo, N. F. / Galstyan, A. G.

Abstract The kinetics and product composition of the liquid-phase catalytic oxidation of toluene with an ozone-air mixture were studied. It was shown that at low temperatures in an acetic anhydride medium in the presence of manganese acetate and an inorganic acid, oxidation develops mainly at the methyl group, yielding benzyl acetate, benzaldehyde, and benzylidene diacetate. The scheme of redox catalysis to explain the experimental data is discussed.

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Kinetics and mechanism of the catalytic reaction of ozone with toluene in the liquid phase

Galstyan, S. G. / Tyupalo, N. F. / Galstyan, A. G.

Abstract The kinetics and product composition of the liquid-phase catalytic oxidation of toluene with an ozone-air mixture were studied. It was shown that at low temperatures in an acetic anhydride medium in the presence of manganese acetate and an inorganic acid, oxidation develops mainly at the methyl group, yielding benzyl acetate, benzaldehyde, and benzylidene diacetate. The scheme of redox catalysis to explain the experimental data is discussed.

Kinetics and mechanism of the catalytic reaction of ozone with toluene in the liquid phase

Galstyan, S. G. / Tyupalo, N. F. / Galstyan, A. G.

Abstract The kinetics and product composition of the liquid-phase catalytic oxidation of toluene with an ozone-air mixture were studied. It was shown that at low temperatures in an acetic anhydride medium in the presence of manganese acetate and an inorganic acid, oxidation develops mainly at the methyl group, yielding benzyl acetate, benzaldehyde, and benzylidene diacetate. The scheme of redox catalysis to explain the experimental data is discussed.

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Title:

Kinetics and mechanism of the catalytic reaction of ozone with toluene in the liquid phase

Contributors:

Galstyan, S. G. (author) / Tyupalo, N. F. (author) / Galstyan, A. G. (author)

Published in:

Petroleum Chemistry ; 51 ; 212-215

Publication date:

2011-05-01

Size:

4 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544111030042

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Ozone , Benzaldehyde , Benzyl Alcohol , Petroleum Chemistry , Redox Catalysis Chemistry , Industrial Chemistry/Chemical Engineering

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