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Oxidation of Propane: Influence of the Nature of Catalyst, Cocatalyst, and Coreductant
https://orcid.org/http://orcid.org/0000-0002-1631-021X
https://orcid.org/http://orcid.org/0000-0003-3128-0837
https://orcid.org/http://orcid.org/0000-0001-8200-0706
Variation of the nature of the components of the catalytic systems comprising a catalyst [Pd/C, Pd(α,α-bipy)Cl2, RhCl3] and a cocatalyst (FeSO4, CuSO4), as well as a coreductant (H2, CO), allows exerting some control over the selectivity of the process of propane oxidation with oxygen. In particular, the yield of carbonyl compounds such as acetone and propanal in the presence of the Pd/C–FeSO4–H2catalytic system reached 90%, and that of propyl esters in the presence of RhCl3–CuSO4–CO catalytic system was 64.5%. These differences are supposedly attributable to the changes in the process mechanism depending on the composition of the catalytic systems.
Oxidation of Propane: Influence of the Nature of Catalyst, Cocatalyst, and Coreductant
https://orcid.org/http://orcid.org/0000-0002-1631-021X
https://orcid.org/http://orcid.org/0000-0003-3128-0837
https://orcid.org/http://orcid.org/0000-0001-8200-0706
Variation of the nature of the components of the catalytic systems comprising a catalyst [Pd/C, Pd(α,α-bipy)Cl2, RhCl3] and a cocatalyst (FeSO4, CuSO4), as well as a coreductant (H2, CO), allows exerting some control over the selectivity of the process of propane oxidation with oxygen. In particular, the yield of carbonyl compounds such as acetone and propanal in the presence of the Pd/C–FeSO4–H2catalytic system reached 90%, and that of propyl esters in the presence of RhCl3–CuSO4–CO catalytic system was 64.5%. These differences are supposedly attributable to the changes in the process mechanism depending on the composition of the catalytic systems.
Oxidation of Propane: Influence of the Nature of Catalyst, Cocatalyst, and Coreductant
https://orcid.org/http://orcid.org/0000-0002-1631-021X
https://orcid.org/http://orcid.org/0000-0003-3128-0837
https://orcid.org/http://orcid.org/0000-0001-8200-0706
Variation of the nature of the components of the catalytic systems comprising a catalyst [Pd/C, Pd(α,α-bipy)Cl2, RhCl3] and a cocatalyst (FeSO4, CuSO4), as well as a coreductant (H2, CO), allows exerting some control over the selectivity of the process of propane oxidation with oxygen. In particular, the yield of carbonyl compounds such as acetone and propanal in the presence of the Pd/C–FeSO4–H2catalytic system reached 90%, and that of propyl esters in the presence of RhCl3–CuSO4–CO catalytic system was 64.5%. These differences are supposedly attributable to the changes in the process mechanism depending on the composition of the catalytic systems.
Oxidation of Propane: Influence of the Nature of Catalyst, Cocatalyst, and Coreductant
Pet. Chem.
Chepaikin, E. G. (author) / Menchikova, G. N. (author) / Pomogailo, S. I. (author)
Petroleum Chemistry ; 61 ; 781-786
2021-07-01
6 pages
Article (Journal)
Electronic Resource
English
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Enhanced photocatalytic H2 production on CdS nanorod using cobalt-phosphate as oxidation cocatalyst
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Enhanced photocatalytic H2 production on CdS nanorod using cobalt-phosphate as oxidation cocatalyst
| British Library Online Contents | 2016
Enhanced photocatalytic H2 production on CdS nanorod using cobalt-phosphate as oxidation cocatalyst
| British Library Online Contents | 2016