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Catalytic transformations of mono- and bis-silyl substituted norbornadienes
Abstract Transformations of 2-trimethylsilylnorbornadiene-2,5 (SNBD) and 2,3-bis(trimethylsilyl)norbornadiene-2,5 (DSNBD) under metathesis and addition polymerization conditions were studied. In the presence of the WCl6/1,1,3,3-tetramethyldisilacyclobutane-1,3 and Cl2(PCy3)2Ru=CHPh catalysts, high-molecular-mass silicon-substituted poly(cyclopentylidene vinylene)s were obtained with yields up to 98%. Under addition polymerization conditions, SNBD and DSNBD dimerized on the nickel(II) naphthenate-methyl alumoxane catalyst to give pentacyclic dimers. Three dimers were detected in the case of SNBD, whereas the exo-trans-exo-cyclodimer alone was exclusively produced from DSNBD. Being inactive in addition homopolymerization, both SNBD and DSBND take part in addition copolymerization with norbornene.
Catalytic transformations of mono- and bis-silyl substituted norbornadienes
Abstract Transformations of 2-trimethylsilylnorbornadiene-2,5 (SNBD) and 2,3-bis(trimethylsilyl)norbornadiene-2,5 (DSNBD) under metathesis and addition polymerization conditions were studied. In the presence of the WCl6/1,1,3,3-tetramethyldisilacyclobutane-1,3 and Cl2(PCy3)2Ru=CHPh catalysts, high-molecular-mass silicon-substituted poly(cyclopentylidene vinylene)s were obtained with yields up to 98%. Under addition polymerization conditions, SNBD and DSNBD dimerized on the nickel(II) naphthenate-methyl alumoxane catalyst to give pentacyclic dimers. Three dimers were detected in the case of SNBD, whereas the exo-trans-exo-cyclodimer alone was exclusively produced from DSNBD. Being inactive in addition homopolymerization, both SNBD and DSBND take part in addition copolymerization with norbornene.
Catalytic transformations of mono- and bis-silyl substituted norbornadienes
Gringolts, M. L. (author) / Bermeshev, M. V. (author) / Nelyubina, Yu. V. (author) / Finkelshtein, E. Sh. (author)
Petroleum Chemistry ; 49 ; 369-376
2009-09-01
8 pages
Article (Journal)
Electronic Resource
English
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