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Oxidation of dibenzothiophene with hydrogen peroxide in ionic liquids

Rakhmanov, E. V. / Wang, Zixiao / Tarakanova, A. V. / Oshchepkov, M. S. / Anisimov, A. V.

Abstract Structurally different ionic liquids have been used as a medium for oxidation of dibenzothiophene with hydrogen peroxide in the presence of niobium pentachloride and oxaazacrown ethers. The maximum degree of oxidative conversion of dibenzothiophene (63%) was achieved in the presence of 5-(1,4,7,10-tet-raoxa-13-azacyclopentadecan-13-yl)pentadecanoic acid, an oxaazacrown ether bearing the carboxylic group in a side chain.

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Oxidation of dibenzothiophene with hydrogen peroxide in ionic liquids

Rakhmanov, E. V. / Wang, Zixiao / Tarakanova, A. V. / Oshchepkov, M. S. / Anisimov, A. V.

Abstract Structurally different ionic liquids have been used as a medium for oxidation of dibenzothiophene with hydrogen peroxide in the presence of niobium pentachloride and oxaazacrown ethers. The maximum degree of oxidative conversion of dibenzothiophene (63%) was achieved in the presence of 5-(1,4,7,10-tet-raoxa-13-azacyclopentadecan-13-yl)pentadecanoic acid, an oxaazacrown ether bearing the carboxylic group in a side chain.

Oxidation of dibenzothiophene with hydrogen peroxide in ionic liquids

Rakhmanov, E. V. / Wang, Zixiao / Tarakanova, A. V. / Oshchepkov, M. S. / Anisimov, A. V.

Abstract Structurally different ionic liquids have been used as a medium for oxidation of dibenzothiophene with hydrogen peroxide in the presence of niobium pentachloride and oxaazacrown ethers. The maximum degree of oxidative conversion of dibenzothiophene (63%) was achieved in the presence of 5-(1,4,7,10-tet-raoxa-13-azacyclopentadecan-13-yl)pentadecanoic acid, an oxaazacrown ether bearing the carboxylic group in a side chain.

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Title:

Oxidation of dibenzothiophene with hydrogen peroxide in ionic liquids

Contributors:

Rakhmanov, E. V. (author) / Wang, Zixiao (author) / Tarakanova, A. V. (author) / Oshchepkov, M. S. (author) / Anisimov, A. V. (author)

Published in:

Petroleum Chemistry ; 52 ; 213-214

Publication date:

2012-05-01

Size:

2 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544112030103

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Ionic Liquid , Macrocycle , Hexade Cane , Petroleum Chemistry , Dibenzothiophene Chemistry , Industrial Chemistry/Chemical Engineering

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