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Catalytic conversion of rape oil into alkane-aromatic fraction in the presence of Pd-Zn/MFI
Abstract Results on the conversion of rape oil into the alkane-aromatic fraction in the presence of a prototype of a MFI-based industrial catalyst (Si/Al = 30) promoted with 0.6 wt % Pd and 1 wt % Zn are presented. It has been shown that an increase in the process temperature from 360 to 420°C leads to a significant increase in the yield of aromatic compounds, and an increase in the substrate space velocity leads to a three-fold increase in the yield of C4–C6 alkanes of primarily the iso-branched structure. The genesis of active Pd and Zn clusters is discussed on the basis of X-ray data.
Catalytic conversion of rape oil into alkane-aromatic fraction in the presence of Pd-Zn/MFI
Abstract Results on the conversion of rape oil into the alkane-aromatic fraction in the presence of a prototype of a MFI-based industrial catalyst (Si/Al = 30) promoted with 0.6 wt % Pd and 1 wt % Zn are presented. It has been shown that an increase in the process temperature from 360 to 420°C leads to a significant increase in the yield of aromatic compounds, and an increase in the substrate space velocity leads to a three-fold increase in the yield of C4–C6 alkanes of primarily the iso-branched structure. The genesis of active Pd and Zn clusters is discussed on the basis of X-ray data.
Catalytic conversion of rape oil into alkane-aromatic fraction in the presence of Pd-Zn/MFI
Tsodikov, M. V. (author) / Chistyakov, A. V. (author) / Gubanov, M. A. (author) / Murzin, V. Yu. (author) / Bukina, Z. M. (author) / Kolesnichenko, N. V. (author) / Khadzhiev, S. N. (author)
Petroleum Chemistry ; 53 ; 46-53
2013-01-01
8 pages
Article (Journal)
Electronic Resource
English
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