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Synthesis of diols from 1,2-epoxy-3-butene

Mel’nik, L. V. / Srednev, S. S. / Rybina, G. V. / Meshechkina, A. E. / Shevchuk, A. S. / Danilova, A. S.

Abstract The catalytic hydration of 1,2-epoxy-3-butene was studied. The products of the reaction are 3-butenediol-1,2(BD-1,2) and 2-butenediol-1,4 (BD-1,4). It was shown that the formation of 2-butenediol-1,4 proceeds predominantly in a polar solvent medium in the presence of the catalytic system “nickel iodide (bromide)-tetraethylammonium iodide” at a temperature of 80°C. In the presence of inorganic acids, the main product is 3-butenediol-1,2.

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Synthesis of diols from 1,2-epoxy-3-butene

Mel’nik, L. V. / Srednev, S. S. / Rybina, G. V. / Meshechkina, A. E. / Shevchuk, A. S. / Danilova, A. S.

Abstract The catalytic hydration of 1,2-epoxy-3-butene was studied. The products of the reaction are 3-butenediol-1,2(BD-1,2) and 2-butenediol-1,4 (BD-1,4). It was shown that the formation of 2-butenediol-1,4 proceeds predominantly in a polar solvent medium in the presence of the catalytic system “nickel iodide (bromide)-tetraethylammonium iodide” at a temperature of 80°C. In the presence of inorganic acids, the main product is 3-butenediol-1,2.

Synthesis of diols from 1,2-epoxy-3-butene

Mel’nik, L. V. / Srednev, S. S. / Rybina, G. V. / Meshechkina, A. E. / Shevchuk, A. S. / Danilova, A. S.

Abstract The catalytic hydration of 1,2-epoxy-3-butene was studied. The products of the reaction are 3-butenediol-1,2(BD-1,2) and 2-butenediol-1,4 (BD-1,4). It was shown that the formation of 2-butenediol-1,4 proceeds predominantly in a polar solvent medium in the presence of the catalytic system “nickel iodide (bromide)-tetraethylammonium iodide” at a temperature of 80°C. In the presence of inorganic acids, the main product is 3-butenediol-1,2.

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Title:

Synthesis of diols from 1,2-epoxy-3-butene

Contributors:

Mel’nik, L. V. (author) / Srednev, S. S. (author) / Rybina, G. V. (author) / Meshechkina, A. E. (author) / Shevchuk, A. S. (author) / Danilova, A. S. (author)

Published in:

Petroleum Chemistry ; 47 ; 201-204

Publication date:

2007-05-01

Size:

4 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544107030085

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Epoxide , Diol , Petroleum Chemistry , Tetrabutylammonium Iodide , Metal Bromide Chemistry , Industrial Chemistry/Chemical Engineering

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