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Dehydrogenation of Light Alkanes (A Review)

Melnikov, D. P. / Novikov, A. A. / Glotov, A. P. / Reshetina, M. V. / Smirnova, E. M. / Wang, H. Q. / Vinokurov, V. A.

Thermodynamic features of thermal and oxidative dehydrogenation of light alkanes, in particular, the dependence of the propane conversion of the temperature, pressure, and CO₂ : propane ratio, are considered. Published data on the use of metal and oxide catalysts for these processes are summarized, and the oxidative dehydrogenation catalysts ensuring the best combination of conversion and selectivity, namely, chromium oxides on mesoporous supports, are revealed. The existing industrial dehydrogenation technologies are discussed.

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Dehydrogenation of Light Alkanes (A Review)

Melnikov, D. P. / Novikov, A. A. / Glotov, A. P. / Reshetina, M. V. / Smirnova, E. M. / Wang, H. Q. / Vinokurov, V. A.

Thermodynamic features of thermal and oxidative dehydrogenation of light alkanes, in particular, the dependence of the propane conversion of the temperature, pressure, and CO₂ : propane ratio, are considered. Published data on the use of metal and oxide catalysts for these processes are summarized, and the oxidative dehydrogenation catalysts ensuring the best combination of conversion and selectivity, namely, chromium oxides on mesoporous supports, are revealed. The existing industrial dehydrogenation technologies are discussed.

Dehydrogenation of Light Alkanes (A Review)

Melnikov, D. P. / Novikov, A. A. / Glotov, A. P. / Reshetina, M. V. / Smirnova, E. M. / Wang, H. Q. / Vinokurov, V. A.

Thermodynamic features of thermal and oxidative dehydrogenation of light alkanes, in particular, the dependence of the propane conversion of the temperature, pressure, and CO₂ : propane ratio, are considered. Published data on the use of metal and oxide catalysts for these processes are summarized, and the oxidative dehydrogenation catalysts ensuring the best combination of conversion and selectivity, namely, chromium oxides on mesoporous supports, are revealed. The existing industrial dehydrogenation technologies are discussed.

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Title:

Dehydrogenation of Light Alkanes (A Review)

Additional title:

Pet. Chem.

Contributors:

Melnikov, D. P. (author) / Novikov, A. A. (author) / Glotov, A. P. (author) / Reshetina, M. V. (author) / Smirnova, E. M. (author) / Wang, H. Q. (author) / Vinokurov, V. A. (author)

Published in:

Petroleum Chemistry ; 62 ; 1027-1046

Publication date:

2022-09-01

Size:

20 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S096554412209006

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

dehydrogenation of alkanes , dehydrogenation with carbon dioxide , production of olefins , propane , propylene , carbon dioxide Chemistry , Industrial Chemistry/Chemical Engineering , Chemistry and Materials Science

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