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Production of aromatic acids and the utilization of polychlorobiphenyls dioxin-like dielectrics by means of aryl halide carbonylation

Zhesko, T. E. / Boyarskii, V. P. / Lanina, S. A. / Nikitina, A. G. / Tereshchenko, G. F.

Abstract An universal method is presented for the synthesis of a wide range of aromatic acids via the reaction of carbonylation of appropriate halides under very mild conditions in the presence of cobalt carbonyl-based catalysts. The basic principles of a flexible manufacturing process for the manufacture of practically important acids and their derivatives were developed. The proposed process was successfully used for the utilization of the ecotoxicants polychlorobiphenyls used as dielectrics with a very high heat resistance.

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Production of aromatic acids and the utilization of polychlorobiphenyls dioxin-like dielectrics by means of aryl halide carbonylation

Zhesko, T. E. / Boyarskii, V. P. / Lanina, S. A. / Nikitina, A. G. / Tereshchenko, G. F.

Abstract An universal method is presented for the synthesis of a wide range of aromatic acids via the reaction of carbonylation of appropriate halides under very mild conditions in the presence of cobalt carbonyl-based catalysts. The basic principles of a flexible manufacturing process for the manufacture of practically important acids and their derivatives were developed. The proposed process was successfully used for the utilization of the ecotoxicants polychlorobiphenyls used as dielectrics with a very high heat resistance.

Production of aromatic acids and the utilization of polychlorobiphenyls dioxin-like dielectrics by means of aryl halide carbonylation

Zhesko, T. E. / Boyarskii, V. P. / Lanina, S. A. / Nikitina, A. G. / Tereshchenko, G. F.

Abstract An universal method is presented for the synthesis of a wide range of aromatic acids via the reaction of carbonylation of appropriate halides under very mild conditions in the presence of cobalt carbonyl-based catalysts. The basic principles of a flexible manufacturing process for the manufacture of practically important acids and their derivatives were developed. The proposed process was successfully used for the utilization of the ecotoxicants polychlorobiphenyls used as dielectrics with a very high heat resistance.

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Title:

Production of aromatic acids and the utilization of polychlorobiphenyls dioxin-like dielectrics by means of aryl halide carbonylation

Contributors:

Zhesko, T. E. (author) / Boyarskii, V. P. (author) / Lanina, S. A. (author) / Nikitina, A. G. (author) / Tereshchenko, G. F. (author)

Published in:

Petroleum Chemistry ; 47 ; 268-272

Publication date:

2007-07-01

Size:

5 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544107040068

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Persistent Organic Pollutant , Petroleum Chemistry , Aryl Halide , Benzyl Chloride , Aromatic Acid Chemistry , Industrial Chemistry/Chemical Engineering

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