Initiated and Inhibited Oxidation of 1,1-Dichloro-2-Methyl-2-Vinylcyclopropane: Fid-Bau Portal

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Initiated and Inhibited Oxidation of 1,1-Dichloro-2-Methyl-2-Vinylcyclopropane

Baiburtli, A. V. / Raskil’dina, G. Z. / Zlotskii, S. S. / Pliss, E. M.

Initiated and inhibited oxidation of 2-methyl-2-vinyl-gem-dichlorocyclopropane has been studied. It has been found that in the oxidation process, chain propagation occurs via the addition of a polyperoxy radical to the double bond. The studied monomer is close to methacrylic acid esters in activity. The inhibiting effect of phenol and amine antioxidants and stable nitroxyl radicals on the radical chain oxidation of 2-methyl-2-vinyl-gem-dichlorocyclopropane has been examined, and amines and nitroxyls have been shown to repeatedly terminate chains due to the regeneration of the inhibitor.

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Initiated and Inhibited Oxidation of 1,1-Dichloro-2-Methyl-2-Vinylcyclopropane

Baiburtli, A. V. / Raskil’dina, G. Z. / Zlotskii, S. S. / Pliss, E. M.

Initiated and inhibited oxidation of 2-methyl-2-vinyl-gem-dichlorocyclopropane has been studied. It has been found that in the oxidation process, chain propagation occurs via the addition of a polyperoxy radical to the double bond. The studied monomer is close to methacrylic acid esters in activity. The inhibiting effect of phenol and amine antioxidants and stable nitroxyl radicals on the radical chain oxidation of 2-methyl-2-vinyl-gem-dichlorocyclopropane has been examined, and amines and nitroxyls have been shown to repeatedly terminate chains due to the regeneration of the inhibitor.

Initiated and Inhibited Oxidation of 1,1-Dichloro-2-Methyl-2-Vinylcyclopropane

Baiburtli, A. V. / Raskil’dina, G. Z. / Zlotskii, S. S. / Pliss, E. M.

Initiated and inhibited oxidation of 2-methyl-2-vinyl-gem-dichlorocyclopropane has been studied. It has been found that in the oxidation process, chain propagation occurs via the addition of a polyperoxy radical to the double bond. The studied monomer is close to methacrylic acid esters in activity. The inhibiting effect of phenol and amine antioxidants and stable nitroxyl radicals on the radical chain oxidation of 2-methyl-2-vinyl-gem-dichlorocyclopropane has been examined, and amines and nitroxyls have been shown to repeatedly terminate chains due to the regeneration of the inhibitor.

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Title:

Initiated and Inhibited Oxidation of 1,1-Dichloro-2-Methyl-2-Vinylcyclopropane

Additional title:

Pet. Chem.

Contributors:

Baiburtli, A. V. (author) / Raskil’dina, G. Z. (author) / Zlotskii, S. S. (author) / Pliss, E. M. (author)

Published in:

Petroleum Chemistry ; 60 ; 51-54

Publication date:

2020-01-01

Size:

4 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S096554412001003X

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

initiated and inhibited oxidation , radical chain oxidation , 2-methyl-2-vinyl-<italic>gem</italic>-dichlorocyclopropane , phenol and amine antioxidants , nitroxyl radicals Chemistry , Industrial Chemistry/Chemical Engineering , Chemistry and Materials Science

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