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Control of Intramolecular Interferences Through Benzene and Cyclophane Using Donor and Acceptor Groups

Sautet, P. / Joachim, C.

Abstract The elastic scattering quantum chemistry method is used to calculate electron transmission through donor-acceptor substituted benzene and cyclophane embedded in a (CH)x infinit chain. Through benzene interferences are controlled by these substituants either directly grafted on the ring or grafted on the other cyclophane ring. The cyclophane structure open a new way in the control of intramolecular interference due to the spatial separation in this molecule between the tunnelling channels and the polarization groups.

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Control of Intramolecular Interferences Through Benzene and Cyclophane Using Donor and Acceptor Groups

Sautet, P. / Joachim, C.

Abstract The elastic scattering quantum chemistry method is used to calculate electron transmission through donor-acceptor substituted benzene and cyclophane embedded in a (CH)x infinit chain. Through benzene interferences are controlled by these substituants either directly grafted on the ring or grafted on the other cyclophane ring. The cyclophane structure open a new way in the control of intramolecular interference due to the spatial separation in this molecule between the tunnelling channels and the polarization groups.

Control of Intramolecular Interferences Through Benzene and Cyclophane Using Donor and Acceptor Groups

Sautet, P. / Joachim, C.

Abstract The elastic scattering quantum chemistry method is used to calculate electron transmission through donor-acceptor substituted benzene and cyclophane embedded in a (CH)x infinit chain. Through benzene interferences are controlled by these substituants either directly grafted on the ring or grafted on the other cyclophane ring. The cyclophane structure open a new way in the control of intramolecular interference due to the spatial separation in this molecule between the tunnelling channels and the polarization groups.

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Title:

Control of Intramolecular Interferences Through Benzene and Cyclophane Using Donor and Acceptor Groups

Contributors:

Sautet, P. (author) / Joachim, C. (author)

Published in:

Conjugated Polymeric Materials: Opportunities in Electronics, Optoelectronics, and Molecular Electronics ; 531-543

NATO ASI Series ; 182

Publication date:

1990-01-01

Size:

13 pages

ISBN:

978-94-010-7416-2 , 978-94-009-2041-5

ISSN:

DOI:

https://doi.org/10.1007/978-94-009-2041-5_42

Type of media:

Article/Chapter (Book)

Type of material:

Electronic Resource

Language:

English

Keywords:

Interference Pattern , Acceptor Group , Bloch Wave , Tunnelling Channel , Conducting Chain Chemistry , Industrial Chemistry/Chemical Engineering , Characterization and Evaluation of Materials , Organic Chemistry , Optics, Lasers, Photonics, Optical Devices

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