A platform for research: civil engineering, architecture and urbanism
A platform for research: civil engineering, architecture and urbanism
Partial Oxidation of Propane: Single-Site Pd/γ-Al2O3 Catalysts
https://orcid.org/https://orcid.org/0000-0002-1631-021X
https://orcid.org/https://orcid.org/0000-0003-3128-0837
https://orcid.org/https://orcid.org/0000-0001-8200-0706
https://orcid.org/https://orcid.org/0000-0002-2673-0453
https://orcid.org/https://orcid.org/0000-0003-2312-3583
The paper proposes a method for synthesizing a heterogeneous catalyst that contains single Pd sites on γ-Al2O3 surface. This method involves preliminary heterogenization of a Pd complex with a hydroxyquinone (e.g., alizarin) on the γ-Al2O3 surface, followed by hydrogenolysis of the Pd–alizarin bond, reduction of Pd(II) into Pd(0), and removal of alizarin. The catalyst was examined by diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and tested in propane oxidation into key petrochemicals. During the test, the catalyst exhibited high activity (242 mol of the product per g-at Pd per hour).
Partial Oxidation of Propane: Single-Site Pd/γ-Al2O3 Catalysts
https://orcid.org/https://orcid.org/0000-0002-1631-021X
https://orcid.org/https://orcid.org/0000-0003-3128-0837
https://orcid.org/https://orcid.org/0000-0001-8200-0706
https://orcid.org/https://orcid.org/0000-0002-2673-0453
https://orcid.org/https://orcid.org/0000-0003-2312-3583
The paper proposes a method for synthesizing a heterogeneous catalyst that contains single Pd sites on γ-Al2O3 surface. This method involves preliminary heterogenization of a Pd complex with a hydroxyquinone (e.g., alizarin) on the γ-Al2O3 surface, followed by hydrogenolysis of the Pd–alizarin bond, reduction of Pd(II) into Pd(0), and removal of alizarin. The catalyst was examined by diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and tested in propane oxidation into key petrochemicals. During the test, the catalyst exhibited high activity (242 mol of the product per g-at Pd per hour).
Partial Oxidation of Propane: Single-Site Pd/γ-Al2O3 Catalysts
https://orcid.org/https://orcid.org/0000-0002-1631-021X
https://orcid.org/https://orcid.org/0000-0003-3128-0837
https://orcid.org/https://orcid.org/0000-0001-8200-0706
https://orcid.org/https://orcid.org/0000-0002-2673-0453
https://orcid.org/https://orcid.org/0000-0003-2312-3583
The paper proposes a method for synthesizing a heterogeneous catalyst that contains single Pd sites on γ-Al2O3 surface. This method involves preliminary heterogenization of a Pd complex with a hydroxyquinone (e.g., alizarin) on the γ-Al2O3 surface, followed by hydrogenolysis of the Pd–alizarin bond, reduction of Pd(II) into Pd(0), and removal of alizarin. The catalyst was examined by diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and tested in propane oxidation into key petrochemicals. During the test, the catalyst exhibited high activity (242 mol of the product per g-at Pd per hour).
Partial Oxidation of Propane: Single-Site Pd/γ-Al2O3 Catalysts
Pet. Chem.
Chepaikin, E. G. (author) / Menchikova, G. N. (author) / Pomogailo, S. I. (author) / Tkachenko, O. P. (author) / Kustov, L. M. (author)
Petroleum Chemistry ; 63 ; 463-467
2023-04-01
5 pages
Article (Journal)
Electronic Resource
English
Evolution of MoTeOx/SiO2 and MoBiTeOx/SiO2 catalysts in the partial oxidation of propane to acrolein
| British Library Online Contents | 2010
| British Library Online Contents | 2010
Homogeneous Metal-Complex Catalyst Systems in the Partial Oxidation of Propane with Oxygen
| Springer Verlag | 2020
Oxidation of Toluene on γ-Al2O3 Supported Copper–Manganese Catalysts
British Library Online Contents | 2011
| British Library Online Contents | 2018