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Styrene oligomerization catalyzed by zeolites of different structural types

Grigor’eva, N. G. / Talipova, R. R. / Korzhova, L. Ph. / Bubennov, S. V. / Kutepov, B. I. / Dzhemilev, U. M.

Abstract It was shown that styrene oligomerization in the presence of the zeolite ZSM-12 in a solvent (chlorobenzene) as well as without it proceeds with a high conversion (98–100 wt %) and a high selectivity for linear dimers (up to 82%). The main oligomerization products in the presence of the zeolite Beta are dimers (70–80%), mostly the linear isomer trans-1,3-diphenylbut-1-ene. In the presence of the less active zeolite Y, styrene gives a complex mixture of oligomers in which dimers (53–60%, in chlorobenzene) or dimers and trimers (60–80%, in bulk) are predominant.

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Styrene oligomerization catalyzed by zeolites of different structural types

Grigor’eva, N. G. / Talipova, R. R. / Korzhova, L. Ph. / Bubennov, S. V. / Kutepov, B. I. / Dzhemilev, U. M.

Abstract It was shown that styrene oligomerization in the presence of the zeolite ZSM-12 in a solvent (chlorobenzene) as well as without it proceeds with a high conversion (98–100 wt %) and a high selectivity for linear dimers (up to 82%). The main oligomerization products in the presence of the zeolite Beta are dimers (70–80%), mostly the linear isomer trans-1,3-diphenylbut-1-ene. In the presence of the less active zeolite Y, styrene gives a complex mixture of oligomers in which dimers (53–60%, in chlorobenzene) or dimers and trimers (60–80%, in bulk) are predominant.

Styrene oligomerization catalyzed by zeolites of different structural types

Grigor’eva, N. G. / Talipova, R. R. / Korzhova, L. Ph. / Bubennov, S. V. / Kutepov, B. I. / Dzhemilev, U. M.

Abstract It was shown that styrene oligomerization in the presence of the zeolite ZSM-12 in a solvent (chlorobenzene) as well as without it proceeds with a high conversion (98–100 wt %) and a high selectivity for linear dimers (up to 82%). The main oligomerization products in the presence of the zeolite Beta are dimers (70–80%), mostly the linear isomer trans-1,3-diphenylbut-1-ene. In the presence of the less active zeolite Y, styrene gives a complex mixture of oligomers in which dimers (53–60%, in chlorobenzene) or dimers and trimers (60–80%, in bulk) are predominant.

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Title:

Styrene oligomerization catalyzed by zeolites of different structural types

Contributors:

Grigor’eva, N. G. (author) / Talipova, R. R. (author) / Korzhova, L. Ph. (author) / Bubennov, S. V. (author) / Kutepov, B. I. (author) / Dzhemilev, U. M. (author)

Published in:

Petroleum Chemistry ; 50 ; 129-134

Publication date:

2010-03-01

Size:

6 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544110020088

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Zeolite , Styrene , Chlorobenzene , Petroleum Chemistry , Lewis Acid Site Chemistry , Industrial Chemistry/Chemical Engineering

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