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Mechanisms for Excited Neutral and Negative and Positive Ion Desorption from Surfaces
Abstract Previous work in electron/photon stimulated desorption (ESD/PSD), utilizing a variety of experimental and theoretical tools, has provided considerable progress towards our understanding of the desorption of ions from covalent systems [1–3]. Comparative investigations of dissociation processes in gas phase, condensed (solid), and chemisorbed systems (e.g.,CO(g), CO(s), and CO/Ru (001), or H2O(g), H2O(s), and OH/Ti) have been very helpful in understanding the desorption of ions from molecularly chemisorbed systems [4,5]. Identification of the excited ionic states responsible for the dissociation or desorption, which can often be made by comparison with photoemission and electron-electron coincidence data, reveals that they possess widely different electronic character and hence arise from widely different excitation mechanisms [4,5].
Mechanisms for Excited Neutral and Negative and Positive Ion Desorption from Surfaces
Abstract Previous work in electron/photon stimulated desorption (ESD/PSD), utilizing a variety of experimental and theoretical tools, has provided considerable progress towards our understanding of the desorption of ions from covalent systems [1–3]. Comparative investigations of dissociation processes in gas phase, condensed (solid), and chemisorbed systems (e.g.,CO(g), CO(s), and CO/Ru (001), or H2O(g), H2O(s), and OH/Ti) have been very helpful in understanding the desorption of ions from molecularly chemisorbed systems [4,5]. Identification of the excited ionic states responsible for the dissociation or desorption, which can often be made by comparison with photoemission and electron-electron coincidence data, reveals that they possess widely different electronic character and hence arise from widely different excitation mechanisms [4,5].
Mechanisms for Excited Neutral and Negative and Positive Ion Desorption from Surfaces
Ramaker, David E. (author)
1985-01-01
14 pages
Article/Chapter (Book)
Electronic Resource
English
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