Synthesis of ethylbenzene on zeolite catalysts: Fid-Bau Portal

Fachinformationsdienst BAUdigital

A platform for research: civil engineering, architecture and urbanism

Synthesis of ethylbenzene on zeolite catalysts

Gerzeliev, I. M. / Myachin, S. I. / Tasueva, I. D. / Khadzhiev, S. N.

Abstract Scaling of the process for zeolite-catalyzed ethylbenzene synthesis used as an example is shown, and the catalyst characteristics and product yields are given. The properties of the catalysts and their stability were studied in laboratory, micro-pilot, pilot, and demonstration units with reactor volumes of 0.01, 1, 100, and 1000 dm3, respectively, a sequence that, in combination with the selection of an optimal catalyst, made it possible to determine more exactly the role of each scaling level. The design of the last reactor was practically identical to that of the industrial reactor. The results of the experiments showed that the product quality and the catalyst service life were the same in the pilot and demonstration reactors operating at identical temperatures, feedstock compositions, and olefin space velocities. To confirm the results under conditions identical to those of an industrial reactor and to devise a mathematical model of the process, the pilot and demonstration units used were designed in such a manner that the basic engineering principles of the industrial reaction could be verified. As a result, the domestic technology of industrial-scale ethylbenzene production on heterogeneous catalysts was implemented.

Access

Check availability in my library

Order at Subito €

Page navigation

Document information

Export, share and cite

Synthesis of ethylbenzene on zeolite catalysts

Gerzeliev, I. M. / Myachin, S. I. / Tasueva, I. D. / Khadzhiev, S. N.

Abstract Scaling of the process for zeolite-catalyzed ethylbenzene synthesis used as an example is shown, and the catalyst characteristics and product yields are given. The properties of the catalysts and their stability were studied in laboratory, micro-pilot, pilot, and demonstration units with reactor volumes of 0.01, 1, 100, and 1000 dm3, respectively, a sequence that, in combination with the selection of an optimal catalyst, made it possible to determine more exactly the role of each scaling level. The design of the last reactor was practically identical to that of the industrial reactor. The results of the experiments showed that the product quality and the catalyst service life were the same in the pilot and demonstration reactors operating at identical temperatures, feedstock compositions, and olefin space velocities. To confirm the results under conditions identical to those of an industrial reactor and to devise a mathematical model of the process, the pilot and demonstration units used were designed in such a manner that the basic engineering principles of the industrial reaction could be verified. As a result, the domestic technology of industrial-scale ethylbenzene production on heterogeneous catalysts was implemented.

Synthesis of ethylbenzene on zeolite catalysts

Gerzeliev, I. M. / Myachin, S. I. / Tasueva, I. D. / Khadzhiev, S. N.

Abstract Scaling of the process for zeolite-catalyzed ethylbenzene synthesis used as an example is shown, and the catalyst characteristics and product yields are given. The properties of the catalysts and their stability were studied in laboratory, micro-pilot, pilot, and demonstration units with reactor volumes of 0.01, 1, 100, and 1000 dm3, respectively, a sequence that, in combination with the selection of an optimal catalyst, made it possible to determine more exactly the role of each scaling level. The design of the last reactor was practically identical to that of the industrial reactor. The results of the experiments showed that the product quality and the catalyst service life were the same in the pilot and demonstration reactors operating at identical temperatures, feedstock compositions, and olefin space velocities. To confirm the results under conditions identical to those of an industrial reactor and to devise a mathematical model of the process, the pilot and demonstration units used were designed in such a manner that the basic engineering principles of the industrial reaction could be verified. As a result, the domestic technology of industrial-scale ethylbenzene production on heterogeneous catalysts was implemented.

Access

Check availability in my library

Order at Subito €

Page navigation

Document information

Export, share and cite

Document information

Title:

Synthesis of ethylbenzene on zeolite catalysts

Contributors:

Gerzeliev, I. M. (author) / Myachin, S. I. (author) / Tasueva, I. D. (author) / Khadzhiev, S. N. (author)

Published in:

Petroleum Chemistry ; 49 ; 59-65

Publication date:

2009-01-01

Size:

7 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544109010113

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Zeolite , Petroleum Chemistry , Benzene Alkylation , Ethylbenzene , Zeolite Catalyst Chemistry , Industrial Chemistry/Chemical Engineering

Similar titles

Erratum to: “Synthesis of ethylbenzene on zeolite catalysts”

Gerzeliev, I. M. / Myachin, S. I. / Tasuev, I. D. et al. | Springer Verlag | 2009

Free access

Ethylbenzene synthesis and benzene transalkylation with diethylbenzenes on zeolite catalysts

Gerzeliev, I. M. / Khadzhiev, S. N. / Sakharova, I. E. | Springer Verlag | 2011

Hydroalkylation of benzene and ethylbenzene over metal-containing zeolite catalysts

Borodina, I. B. / Ponomareva, O. A. / Yushchenko, V. V. et al. | Springer Verlag | 2009

The Hydrogenation of Ethylbenzene over Nano NiMo Catalysts

Sheng, J. / Yi, X. / Xie, Q. et al. | British Library Online Contents | 2009

Oxidative dehydrogenation of ethylbenzene on vanadium-magnesium oxide catalysts

Volkov, R.N. / Panova, V.P. / Belomestnykh, I.P. et al. | Elsevier | 1984