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Zn(II) Complex Catalyzed Coupling Aquathermolysis of Water-Heavy Oil-Methanol at Low Temperature

Chen, Gang / Yuan, Weihua / Yan, Jiao / Meng, Mei / Guo, Zheng / Gu, Xuefan / Zhang, Jie / Qu, Chengtun / Song, Hua / Jeje, Ayodeji

Abstract A Zn(II) coordination complex was synthesized, characterized, and used for catalytic aquathermolysis of heavy oil at low temperatures for the first time. The effects of water content and catalyst concentration on aquathermolysis were investigated. And then a tri-component coupling aquathermolysis of waterheavy oil-methanol was designed and the reaction conditions were investigated. With the catalyst and methanol, the reaction occurred at temperatures as low as 180°C. The viscosity of the product was also substantially reduced from around 24 400 to 6420 mPa s by the decomposition of the large hydrocarbon molecules.

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Zn(II) Complex Catalyzed Coupling Aquathermolysis of Water-Heavy Oil-Methanol at Low Temperature

Chen, Gang / Yuan, Weihua / Yan, Jiao / Meng, Mei / Guo, Zheng / Gu, Xuefan / Zhang, Jie / Qu, Chengtun / Song, Hua / Jeje, Ayodeji

Abstract A Zn(II) coordination complex was synthesized, characterized, and used for catalytic aquathermolysis of heavy oil at low temperatures for the first time. The effects of water content and catalyst concentration on aquathermolysis were investigated. And then a tri-component coupling aquathermolysis of waterheavy oil-methanol was designed and the reaction conditions were investigated. With the catalyst and methanol, the reaction occurred at temperatures as low as 180°C. The viscosity of the product was also substantially reduced from around 24 400 to 6420 mPa s by the decomposition of the large hydrocarbon molecules.

Zn(II) Complex Catalyzed Coupling Aquathermolysis of Water-Heavy Oil-Methanol at Low Temperature

Chen, Gang / Yuan, Weihua / Yan, Jiao / Meng, Mei / Guo, Zheng / Gu, Xuefan / Zhang, Jie / Qu, Chengtun / Song, Hua / Jeje, Ayodeji

Abstract A Zn(II) coordination complex was synthesized, characterized, and used for catalytic aquathermolysis of heavy oil at low temperatures for the first time. The effects of water content and catalyst concentration on aquathermolysis were investigated. And then a tri-component coupling aquathermolysis of waterheavy oil-methanol was designed and the reaction conditions were investigated. With the catalyst and methanol, the reaction occurred at temperatures as low as 180°C. The viscosity of the product was also substantially reduced from around 24 400 to 6420 mPa s by the decomposition of the large hydrocarbon molecules.

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Title:

Zn(II) Complex Catalyzed Coupling Aquathermolysis of Water-Heavy Oil-Methanol at Low Temperature

Contributors:

Chen, Gang (author) / Yuan, Weihua (author) / Yan, Jiao (author) / Meng, Mei (author) / Guo, Zheng (author) / Gu, Xuefan (author) / Zhang, Jie (author) / Qu, Chengtun (author) / Song, Hua (author) / Jeje, Ayodeji (author)

Published in:

Petroleum Chemistry ; 58 ; 197-202

Publication date:

2018-03-01

Size:

6 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544118030039

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

heavy oil , catalytic aquathermolysis , viscosity reduction , coordination complex , methanol Chemistry , Industrial Chemistry/Chemical Engineering

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