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Reductive dimerization and oligomerization of alcohols, ketones, and aldehydes to hydrocarbons on a promoted, fused iron catalyst

Glebov, L. S. / Zaikin, V. G. / Mikaya, A. I. / Kliger, G. A.

Abstract A new reductive dimerization and oligomerization reaction of (C5 and C6) cycloalkanols and cycloalkanones, benzaldehyde, and benzyl alcohol to hydrocarbons containing as many, or more, carbon atoms as the reactant oxygenated compound on a promoted, fused iron catalyst proceeds at a temperature of 250–350°C, a hydrogen pressure of 0.1–1 MPa, a specific feed rate of oxygenated reagent of 80–320 g h−1kg−1Ct, and a hydrogen space velocity of 1 × 103 to 20 × 103 h−1. Possible reaction mechanisms have been considered.

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Reductive dimerization and oligomerization of alcohols, ketones, and aldehydes to hydrocarbons on a promoted, fused iron catalyst

Glebov, L. S. / Zaikin, V. G. / Mikaya, A. I. / Kliger, G. A.

Abstract A new reductive dimerization and oligomerization reaction of (C5 and C6) cycloalkanols and cycloalkanones, benzaldehyde, and benzyl alcohol to hydrocarbons containing as many, or more, carbon atoms as the reactant oxygenated compound on a promoted, fused iron catalyst proceeds at a temperature of 250–350°C, a hydrogen pressure of 0.1–1 MPa, a specific feed rate of oxygenated reagent of 80–320 g h−1kg−1Ct, and a hydrogen space velocity of 1 × 103 to 20 × 103 h−1. Possible reaction mechanisms have been considered.

Reductive dimerization and oligomerization of alcohols, ketones, and aldehydes to hydrocarbons on a promoted, fused iron catalyst

Glebov, L. S. / Zaikin, V. G. / Mikaya, A. I. / Kliger, G. A.

Abstract A new reductive dimerization and oligomerization reaction of (C5 and C6) cycloalkanols and cycloalkanones, benzaldehyde, and benzyl alcohol to hydrocarbons containing as many, or more, carbon atoms as the reactant oxygenated compound on a promoted, fused iron catalyst proceeds at a temperature of 250–350°C, a hydrogen pressure of 0.1–1 MPa, a specific feed rate of oxygenated reagent of 80–320 g h−1kg−1Ct, and a hydrogen space velocity of 1 × 103 to 20 × 103 h−1. Possible reaction mechanisms have been considered.

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Title:

Reductive dimerization and oligomerization of alcohols, ketones, and aldehydes to hydrocarbons on a promoted, fused iron catalyst

Contributors:

Glebov, L. S. (author) / Zaikin, V. G. (author) / Mikaya, A. I. (author) / Kliger, G. A. (author)

Published in:

Petroleum Chemistry ; 54 ; 296-308

Publication date:

2014-07-01

Size:

13 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544114040045

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

oligomerization , alcohols , ketones , aldehydes , fused iron catalyst Chemistry , Industrial Chemistry/Chemical Engineering

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