Mesoporous Gallium-Based Catalysts for Oxidative Dehydrogenation of Propane in the Presence of Carbon Dioxide: Fid-Bau Portal

Fachinformationsdienst BAUdigital

A platform for research: civil engineering, architecture and urbanism

Mesoporous Gallium-Based Catalysts for Oxidative Dehydrogenation of Propane in the Presence of Carbon Dioxide

Melnikov, D. P. / Smirnova, E. M. / Reshetina, M. V. / Glotov, A. P. / Novikov, A. A. / Gushchin, P. A. / Wang, H. Q. / Vinokurov, V. A.

The present study investigates a series of gallium-based catalysts supported on natural and composite aluminosilicate mesoporous supports in the CO₂-assisted oxidative dehydrogenation of propane. The catalyst supports were prepared by mixing a functional material with a boehmite binder, the functional materials being derived from natural halloysite nanotubes (HNTs). Three different supports were used: pristine HNTs; HNTs with MCM-41 synthesized around halloysite; and HNTs with MCM-41 synthesized inside the halloysite lumen. The CO₂-assisted oxidative propane dehydrogenation was tested in the range of 550–700°C at a CO₂/C₃H₈ molar ratio of 2.0. All the catalysts showed comparable propane conversion (from 10–13% to 70–80%) and propylene selectivity (from 80–84 to 30–32%). The highest propylene space-time yield (6.5 mol kg_cat^–1 h^–1) was observed for the Ga/HNT catalyst at 650°C.

Access

Check availability in my library

Order at Subito €

Page navigation

Document information

Export, share and cite

Mesoporous Gallium-Based Catalysts for Oxidative Dehydrogenation of Propane in the Presence of Carbon Dioxide

Melnikov, D. P. / Smirnova, E. M. / Reshetina, M. V. / Glotov, A. P. / Novikov, A. A. / Gushchin, P. A. / Wang, H. Q. / Vinokurov, V. A.

The present study investigates a series of gallium-based catalysts supported on natural and composite aluminosilicate mesoporous supports in the CO₂-assisted oxidative dehydrogenation of propane. The catalyst supports were prepared by mixing a functional material with a boehmite binder, the functional materials being derived from natural halloysite nanotubes (HNTs). Three different supports were used: pristine HNTs; HNTs with MCM-41 synthesized around halloysite; and HNTs with MCM-41 synthesized inside the halloysite lumen. The CO₂-assisted oxidative propane dehydrogenation was tested in the range of 550–700°C at a CO₂/C₃H₈ molar ratio of 2.0. All the catalysts showed comparable propane conversion (from 10–13% to 70–80%) and propylene selectivity (from 80–84 to 30–32%). The highest propylene space-time yield (6.5 mol kg_cat^–1 h^–1) was observed for the Ga/HNT catalyst at 650°C.

Mesoporous Gallium-Based Catalysts for Oxidative Dehydrogenation of Propane in the Presence of Carbon Dioxide

Melnikov, D. P. / Smirnova, E. M. / Reshetina, M. V. / Glotov, A. P. / Novikov, A. A. / Gushchin, P. A. / Wang, H. Q. / Vinokurov, V. A.

The present study investigates a series of gallium-based catalysts supported on natural and composite aluminosilicate mesoporous supports in the CO₂-assisted oxidative dehydrogenation of propane. The catalyst supports were prepared by mixing a functional material with a boehmite binder, the functional materials being derived from natural halloysite nanotubes (HNTs). Three different supports were used: pristine HNTs; HNTs with MCM-41 synthesized around halloysite; and HNTs with MCM-41 synthesized inside the halloysite lumen. The CO₂-assisted oxidative propane dehydrogenation was tested in the range of 550–700°C at a CO₂/C₃H₈ molar ratio of 2.0. All the catalysts showed comparable propane conversion (from 10–13% to 70–80%) and propylene selectivity (from 80–84 to 30–32%). The highest propylene space-time yield (6.5 mol kg_cat^–1 h^–1) was observed for the Ga/HNT catalyst at 650°C.

Access

Check availability in my library

Order at Subito €

Page navigation

Document information

Export, share and cite

Document information

Title:

Mesoporous Gallium-Based Catalysts for Oxidative Dehydrogenation of Propane in the Presence of Carbon Dioxide

Additional title:

Pet. Chem.

Contributors:

Melnikov, D. P. (author) / Smirnova, E. M. (author) / Reshetina, M. V. (author) / Glotov, A. P. (author) / Novikov, A. A. (author) / Gushchin, P. A. (author) / Wang, H. Q. (author) / Vinokurov, V. A. (author)

Published in:

Petroleum Chemistry ; 63 ; 1228-1234

Publication date:

2023-10-01

Size:

7 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544123090049

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

gallium-containing catalysts , oxidative dehydrogenation , halloysite , carbon dioxide , propane , propylene Chemistry , Industrial Chemistry/Chemical Engineering , Chemistry and Materials Science

Similar titles

Dehydrogenation of ethylbenzene on oxide catalysts in the presence of carbon dioxide

Fedorov, G.I. / Sibgatullin, Sh.G. / Solodova, N.L. et al. | Elsevier | 1975

Investigation of Aging Mechanism of Pt‐ZSM‐5 Catalysts for Non‐Oxidative Propane Dehydrogenation

Matthies, Jörn H. / Dittmann, Daniel / Dyballa, Michael et al. | Wiley | 2024

Nano-MgO supported CrO"x catalysts applied in propane oxidative dehydrogenation: Relationship between active chromium phases and propane reaction pathway

Ma, F. / Chen, S. / Li, Y. et al. | British Library Online Contents | 2014

Study on the structure, acidic properties of V-Zr nanocrystal catalysts in oxidative dehydrogenation of propane

Chen, S. / Ma, F. / Xu, A. et al. | British Library Online Contents | 2014

Synthesis of Vanadium Catalysts Supported on Cerium Containing TiO2 Nanotubes for the Oxidative Dehydrogenation of Propane

Moghaddam, M. S. / Towfighi, J. | Springer Verlag | 2018