Reactions of <Emphasis Type="Italic">o</Emphasis>-cresol with ozone in acetic anhydride: Fid-Bau Portal

Fachinformationsdienst BAUdigital

A platform for research: civil engineering, architecture and urbanism

Reactions of o-cresol with ozone in acetic anhydride

Galstyan, A. G. / Sedykh, A. A. / Lysak, V. V.

Abstract The kinetics of o-cresol oxidation with ozone in acetic anhydride was studied. It was shown that o-cresol was acylated in acetic anhydride to give o-cresyl acetate. Ozone attacks the C=C bonds of the aromatic ring of o-cresyl acetate to give unsaturated peroxide compounds. The composition of the oxidation products alters when the ozonation is carried out in the presence of catalytic amounts of sulfuric acid. Along with the products of the destructive oxidation of the aromatic ring, the methyl group oxidation products appeared as the acyl derivatives o-acetoxybenzyl alcohol and o-acetoxybenzaldehyde, a form that is more stable toward the action of ozone (10%). The addition of manganese(II) acetate to the reaction mixture increases the methyl group oxidation selectivity to 75%. The mechanism of the ozone reaction with o-cresol in acetic anhydride that explains the obtained results is discussed.

Access

Check availability in my library

Order at Subito €

Page navigation

Document information

Export, share and cite

Reactions of o-cresol with ozone in acetic anhydride

Galstyan, A. G. / Sedykh, A. A. / Lysak, V. V.

Abstract The kinetics of o-cresol oxidation with ozone in acetic anhydride was studied. It was shown that o-cresol was acylated in acetic anhydride to give o-cresyl acetate. Ozone attacks the C=C bonds of the aromatic ring of o-cresyl acetate to give unsaturated peroxide compounds. The composition of the oxidation products alters when the ozonation is carried out in the presence of catalytic amounts of sulfuric acid. Along with the products of the destructive oxidation of the aromatic ring, the methyl group oxidation products appeared as the acyl derivatives o-acetoxybenzyl alcohol and o-acetoxybenzaldehyde, a form that is more stable toward the action of ozone (10%). The addition of manganese(II) acetate to the reaction mixture increases the methyl group oxidation selectivity to 75%. The mechanism of the ozone reaction with o-cresol in acetic anhydride that explains the obtained results is discussed.

Reactions of o-cresol with ozone in acetic anhydride

Galstyan, A. G. / Sedykh, A. A. / Lysak, V. V.

Abstract The kinetics of o-cresol oxidation with ozone in acetic anhydride was studied. It was shown that o-cresol was acylated in acetic anhydride to give o-cresyl acetate. Ozone attacks the C=C bonds of the aromatic ring of o-cresyl acetate to give unsaturated peroxide compounds. The composition of the oxidation products alters when the ozonation is carried out in the presence of catalytic amounts of sulfuric acid. Along with the products of the destructive oxidation of the aromatic ring, the methyl group oxidation products appeared as the acyl derivatives o-acetoxybenzyl alcohol and o-acetoxybenzaldehyde, a form that is more stable toward the action of ozone (10%). The addition of manganese(II) acetate to the reaction mixture increases the methyl group oxidation selectivity to 75%. The mechanism of the ozone reaction with o-cresol in acetic anhydride that explains the obtained results is discussed.

Access

Check availability in my library

Order at Subito €

Page navigation

Document information

Export, share and cite

Document information

Title:

Reactions of o-cresol with ozone in acetic anhydride

Contributors:

Galstyan, A. G. (author) / Sedykh, A. A. (author) / Lysak, V. V. (author)

Published in:

Petroleum Chemistry ; 48 ; 118-122

Publication date:

2008-03-01

Size:

5 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1007/s11494-008-2007-3

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Industrial Chemistry/Chemical Engineering , Chemistry

Similar titles

Reactions of o-cresol with ozone in acetic anhydride

Galstyan, A. G. / Sedykh, A. A. / Lysak, V. V. | Springer Verlag | 2008

Catalytic oxidation of m-cresol acetate in acetic anhydride

Elsevier | 1979

Oxidation of m-cresol acetate in the presence of acetic anhydride (preparation of m-hydroxybenzyl alcohol diacetate)

Bashkirov, A.N. / Vygodskaya, I.V. / Kugel', V.Ya. et al. | Elsevier | 1976

Reactions of Epoxides Prepared from Some Monoterpenes with Acetic Anhydride on Aluminosilicate Catalysts

Tatarova, L. E. / Korchagina, D. V. / Volcho, K. P. et al. | British Library Online Contents | 2003

Reaction of Thiosemicarbazones from Heterocyclic Series with Acetic Anhydride

Elokhina, V. N. / Karnaukhova, R. V. / Nakhmanovich, A. S. et al. | British Library Online Contents | 2002