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Synthesis of adamantane and diamantane hydrocarbons by high-temperature cracking of higher n-alkanes

Gordadze, G. N. / Giruts, M. V.

Abstract Adamantanes and diamantanes, whose abiogenic synthesis from carbon and hydrogen is feasible, were synthesized via the high-temperature cracking of individual n-alkanes in order to reveal the possible ways of the genesis of hydrocarbons with a diamond-like structure. As a result of the high-temperature cracking of n-alkanes, all theoretically possible isomers of C10–C13 adamantanes and C14–C16 diamantanes are formed, as well as n-alkanes up to C35H72 and coke.

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Synthesis of adamantane and diamantane hydrocarbons by high-temperature cracking of higher n-alkanes

Gordadze, G. N. / Giruts, M. V.

Abstract Adamantanes and diamantanes, whose abiogenic synthesis from carbon and hydrogen is feasible, were synthesized via the high-temperature cracking of individual n-alkanes in order to reveal the possible ways of the genesis of hydrocarbons with a diamond-like structure. As a result of the high-temperature cracking of n-alkanes, all theoretically possible isomers of C10–C13 adamantanes and C14–C16 diamantanes are formed, as well as n-alkanes up to C35H72 and coke.

Synthesis of adamantane and diamantane hydrocarbons by high-temperature cracking of higher n-alkanes

Gordadze, G. N. / Giruts, M. V.

Abstract Adamantanes and diamantanes, whose abiogenic synthesis from carbon and hydrogen is feasible, were synthesized via the high-temperature cracking of individual n-alkanes in order to reveal the possible ways of the genesis of hydrocarbons with a diamond-like structure. As a result of the high-temperature cracking of n-alkanes, all theoretically possible isomers of C10–C13 adamantanes and C14–C16 diamantanes are formed, as well as n-alkanes up to C35H72 and coke.

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Title:

Synthesis of adamantane and diamantane hydrocarbons by high-temperature cracking of higher n-alkanes

Contributors:

Gordadze, G. N. (author) / Giruts, M. V. (author)

Published in:

Petroleum Chemistry ; 48 ; 414-419

Publication date:

2008-11-01

Size:

6 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544108060029

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Kerogen , Petroleum Chemistry , Adamantanes , Crystalline Basement , Diamantanes Chemistry , Industrial Chemistry/Chemical Engineering

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