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    Polymerization of Ethylene in the Presence of Titanium(IV), Zirconium(IV), and Vanadium(V) Coordination Compounds with Salen Ligands

    New search for: Gagieva, S. Ch.
    New search for: Tuskaev, V. A.
    New search for: Lyadov, A. S.
    New search for: Takazova, R. U.
    New search for: Bulychev, B. M.

    Coordination compounds of titanium(IV), zirconium(IV), and vanadium(V) with chiral salen ligands have been obtained and characterized, and their catalytic activity in the polymerization reaction of ethylene has been studied. It has been shown that in the presence of polymethylaluminoxane as a cocatalyst, the activity of the titanium-containing catalyst system reaches 944 kgPE mol(Ti)−1 h−1 and leads to the preparation of ultrahigh-molecular-weight polyethylene.

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    Polymerization of Ethylene in the Presence of Titanium(IV), Zirconium(IV), and Vanadium(V) Coordination Compounds with Salen Ligands

    New search for: Gagieva, S. Ch.
    New search for: Tuskaev, V. A.
    New search for: Lyadov, A. S.
    New search for: Takazova, R. U.
    New search for: Bulychev, B. M.

    Coordination compounds of titanium(IV), zirconium(IV), and vanadium(V) with chiral salen ligands have been obtained and characterized, and their catalytic activity in the polymerization reaction of ethylene has been studied. It has been shown that in the presence of polymethylaluminoxane as a cocatalyst, the activity of the titanium-containing catalyst system reaches 944 kgPE mol(Ti)−1 h−1 and leads to the preparation of ultrahigh-molecular-weight polyethylene.

    Access

    Check access
    Check availability in my library
    Order at Subito €

    Polymerization of Ethylene in the Presence of Titanium(IV), Zirconium(IV), and Vanadium(V) Coordination Compounds with Salen Ligands

    New search for: Gagieva, S. Ch.
    New search for: Tuskaev, V. A.
    New search for: Lyadov, A. S.
    New search for: Takazova, R. U.
    New search for: Bulychev, B. M.

    Coordination compounds of titanium(IV), zirconium(IV), and vanadium(V) with chiral salen ligands have been obtained and characterized, and their catalytic activity in the polymerization reaction of ethylene has been studied. It has been shown that in the presence of polymethylaluminoxane as a cocatalyst, the activity of the titanium-containing catalyst system reaches 944 kgPE mol(Ti)−1 h−1 and leads to the preparation of ultrahigh-molecular-weight polyethylene.

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    Title:

    Polymerization of Ethylene in the Presence of Titanium(IV), Zirconium(IV), and Vanadium(V) Coordination Compounds with Salen Ligands

    Additional title:

    Pet. Chem.

    Contributors:

    Gagieva, S. Ch. (author) / Tuskaev, V. A. (author) / Lyadov, A. S. (author) / Takazova, R. U. (author) / Bulychev, B. M. (author)

    Published in:

    Petroleum Chemistry ; 60 ; 291-297

    Publication date:

    2020-03-01

    Size:

    7 pages

    ISSN:

    1555-6239 , 0965-5441

    DOI:

    https://doi.org/10.1134/S0965544120030056

    Type of media:

    Article (Journal)

    Type of material:

    Electronic Resource

    Language:

    English

    Keywords:

    titanium, zirconium, and vanadium compounds , salen ligands , polymerization of ethylene , ultrahigh-molecular-weight polyethylene , olefins , organoaluminum compounds Chemistry , Industrial Chemistry/Chemical Engineering , Chemistry and Materials Science

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