Oligomerization of Unsaturated Compounds in the Presence of Amorphous Mesoporous Aluminosilicates: Fid-Bau Portal

Oligomerization of Unsaturated Compounds in the Presence of Amorphous Mesoporous Aluminosilicates

Bubennov, S. V. / Grigor’eva, N. G. / Serebrennikov, D. V. / Agliullin, M. R. / Kutepov, B. I.

Abstract High activity and selectivity of the samples of ASM amorphous mesoporous aluminosilicates in the synthesis of practically important oligomers of various unsaturated compounds (C5–C16 linear α-olefins, cyclooctene, norbornene, and α-methylstyrene) is found. The oligomerization products obtained in the presence of ASM have a broader molecular weight distribution in comparison with the oligomers synthesized over the H-Beta zeolite. The mesoporous structure of the ASM aluminosilicate provides the preparation of dimers of cyclooctene with high selectivity without cycle opening.

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Oligomerization of Unsaturated Compounds in the Presence of Amorphous Mesoporous Aluminosilicates

Bubennov, S. V. / Grigor’eva, N. G. / Serebrennikov, D. V. / Agliullin, M. R. / Kutepov, B. I.

Abstract

Oligomerization of Unsaturated Compounds in the Presence of Amorphous Mesoporous Aluminosilicates

Bubennov, S. V. / Grigor’eva, N. G. / Serebrennikov, D. V. / Agliullin, M. R. / Kutepov, B. I.

Abstract

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Title:

Oligomerization of Unsaturated Compounds in the Presence of Amorphous Mesoporous Aluminosilicates

Contributors:

Bubennov, S. V. (author) / Grigor’eva, N. G. (author) / Serebrennikov, D. V. (author) / Agliullin, M. R. (author) / Kutepov, B. I. (author)

Published in:

Petroleum Chemistry ; 59 ; 682-690

Publication date:

2019-07-01

Size:

9 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S096554411907003X

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

oligomerization , dimers , oligomers , linear α-olefins , cyclenes , α-methylstyrene , mesoporous aluminosilicates , zeolites Chemistry , Industrial Chemistry/Chemical Engineering

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