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Molecular Weight Distribution — Characterisation by GPC

Nguyen, T. Q. / Kausch, H. H.

Abstract The MWD is probably the single most fundamental property of a polymer (see Molecular Weight Distribution and Mechanical Properties). Depending on the application, MW of polymer materials can encompass an extremely large range extending from several hundreds (paints, coatings, functionalised polymers) to a few million daltons (UHMWPE, high performance fibres). Unlike in the case of small molecules, the assignment of an unequivocal MW to a macromolecular material is not straightforward. Due to the kinetics of polymerization, no synthetic polymer has a unique MW.

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Molecular Weight Distribution — Characterisation by GPC

Nguyen, T. Q. / Kausch, H. H.

Abstract The MWD is probably the single most fundamental property of a polymer (see Molecular Weight Distribution and Mechanical Properties). Depending on the application, MW of polymer materials can encompass an extremely large range extending from several hundreds (paints, coatings, functionalised polymers) to a few million daltons (UHMWPE, high performance fibres). Unlike in the case of small molecules, the assignment of an unequivocal MW to a macromolecular material is not straightforward. Due to the kinetics of polymerization, no synthetic polymer has a unique MW.

Molecular Weight Distribution — Characterisation by GPC

Nguyen, T. Q. / Kausch, H. H.

Abstract The MWD is probably the single most fundamental property of a polymer (see Molecular Weight Distribution and Mechanical Properties). Depending on the application, MW of polymer materials can encompass an extremely large range extending from several hundreds (paints, coatings, functionalised polymers) to a few million daltons (UHMWPE, high performance fibres). Unlike in the case of small molecules, the assignment of an unequivocal MW to a macromolecular material is not straightforward. Due to the kinetics of polymerization, no synthetic polymer has a unique MW.

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Title:

Molecular Weight Distribution — Characterisation by GPC

Contributors:

Nguyen, T. Q. (author) / Kausch, H. H. (author)

Published in:

Mechanical Properties and Testing of Polymers ; 151-155

Polymer Science and Technology Series ; 3

Publication date:

1999-01-01

Size:

5 pages

ISBN:

978-94-015-9231-4 , 978-90-481-4024-4

ISSN:

DOI:

https://doi.org/10.1007/978-94-015-9231-4_33

Type of media:

Article/Chapter (Book)

Type of material:

Electronic Resource

Language:

English

Keywords:

Molecular Weight Distribution , Universal Calibration , Steric Exclusion , Enthalpic Interaction , High Performance Fibre Chemistry , Industrial Chemistry/Chemical Engineering , Characterization and Evaluation of Materials , Mechanics , Polymer Sciences

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