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Selective hydrogenation of diene hydrocarbons over palladium catalysts synthesized by modified electric field-assisted laser ablation

Putilin, F. N. / Shatokhin, A. N. / Guliev, F. F. / Aksenov, I. A. / Kardashev, S. V. / Maksimov, A. L. / Karakhanov, E. A.

Abstract Palladium catalysts have been synthesized by electric field-assisted laser ablation at varying orifice voltage. The catalysts have been characterized by XPS and TEM and tested in the hydrogenation of isoprene and 2,5-dimethylhexadiene-2,4. High catalytic activity has been shown (TOFs = 397 and 158 s−1 for isoprene and 2,5-dimethylhexadiene-2.4, respectively).

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Selective hydrogenation of diene hydrocarbons over palladium catalysts synthesized by modified electric field-assisted laser ablation

Putilin, F. N. / Shatokhin, A. N. / Guliev, F. F. / Aksenov, I. A. / Kardashev, S. V. / Maksimov, A. L. / Karakhanov, E. A.

Abstract Palladium catalysts have been synthesized by electric field-assisted laser ablation at varying orifice voltage. The catalysts have been characterized by XPS and TEM and tested in the hydrogenation of isoprene and 2,5-dimethylhexadiene-2,4. High catalytic activity has been shown (TOFs = 397 and 158 s−1 for isoprene and 2,5-dimethylhexadiene-2.4, respectively).

Selective hydrogenation of diene hydrocarbons over palladium catalysts synthesized by modified electric field-assisted laser ablation

Putilin, F. N. / Shatokhin, A. N. / Guliev, F. F. / Aksenov, I. A. / Kardashev, S. V. / Maksimov, A. L. / Karakhanov, E. A.

Abstract Palladium catalysts have been synthesized by electric field-assisted laser ablation at varying orifice voltage. The catalysts have been characterized by XPS and TEM and tested in the hydrogenation of isoprene and 2,5-dimethylhexadiene-2,4. High catalytic activity has been shown (TOFs = 397 and 158 s−1 for isoprene and 2,5-dimethylhexadiene-2.4, respectively).

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Title:

Selective hydrogenation of diene hydrocarbons over palladium catalysts synthesized by modified electric field-assisted laser ablation

Contributors:

Putilin, F. N. (author) / Shatokhin, A. N. (author) / Guliev, F. F. (author) / Aksenov, I. A. (author) / Kardashev, S. V. (author) / Maksimov, A. L. (author) / Karakhanov, E. A. (author)

Published in:

Petroleum Chemistry ; 55 ; 542-548

Publication date:

2015-09-01

Size:

7 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S096554411503010X

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

electric field-assisted laser ablation , heterogeneous catalysis , eggshell catalysts , ultra-low active component content , palladium Chemistry , Industrial Chemistry/Chemical Engineering

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