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Kinetics of Selective Trimerization of Ethylene to 1-Hexene over Chromium-Based Catalysts
https://orcid.org/https://orcid.org/0000-0002-3332-3741
https://orcid.org/https://orcid.org/0009-0000-2598-3873
https://orcid.org/https://orcid.org/0000-0002-2419-807X
https://orcid.org/https://orcid.org/0009-0006-3223-7215
https://orcid.org/https://orcid.org/0000-0001-9648-4895
This review provides an analysis of prior research on the kinetics of the trimerization of ethylene to 1-hexene over existing chromium-based catalytic systems. It discusses the known mechanisms and reaction steps for the formation of 1-hexene as well as olefin by-products. The effects of catalytic system composition, temperature, pressure, reaction time, and the presence of hydrogen on the kinetics of 1-hexene formation are also touched upon. The kinetic models of ethylene trimerization to 1-hexene known from published literature are presented.
Kinetics of Selective Trimerization of Ethylene to 1-Hexene over Chromium-Based Catalysts
https://orcid.org/https://orcid.org/0000-0002-3332-3741
https://orcid.org/https://orcid.org/0009-0000-2598-3873
https://orcid.org/https://orcid.org/0000-0002-2419-807X
https://orcid.org/https://orcid.org/0009-0006-3223-7215
https://orcid.org/https://orcid.org/0000-0001-9648-4895
This review provides an analysis of prior research on the kinetics of the trimerization of ethylene to 1-hexene over existing chromium-based catalytic systems. It discusses the known mechanisms and reaction steps for the formation of 1-hexene as well as olefin by-products. The effects of catalytic system composition, temperature, pressure, reaction time, and the presence of hydrogen on the kinetics of 1-hexene formation are also touched upon. The kinetic models of ethylene trimerization to 1-hexene known from published literature are presented.
Kinetics of Selective Trimerization of Ethylene to 1-Hexene over Chromium-Based Catalysts
https://orcid.org/https://orcid.org/0000-0002-3332-3741
https://orcid.org/https://orcid.org/0009-0000-2598-3873
https://orcid.org/https://orcid.org/0000-0002-2419-807X
https://orcid.org/https://orcid.org/0009-0006-3223-7215
https://orcid.org/https://orcid.org/0000-0001-9648-4895
This review provides an analysis of prior research on the kinetics of the trimerization of ethylene to 1-hexene over existing chromium-based catalytic systems. It discusses the known mechanisms and reaction steps for the formation of 1-hexene as well as olefin by-products. The effects of catalytic system composition, temperature, pressure, reaction time, and the presence of hydrogen on the kinetics of 1-hexene formation are also touched upon. The kinetic models of ethylene trimerization to 1-hexene known from published literature are presented.
Kinetics of Selective Trimerization of Ethylene to 1-Hexene over Chromium-Based Catalysts
Pet. Chem.
Faingol’d, E. E. (author) / Lashmanov, N. N. (author) / Saratovskikh, S. L. (author) / Kulchakovsky, P. I. (author) / Lenev, D. A. (author) / Shamukaev, V. A. (author) / Sedov, I. V. (author)
Petroleum Chemistry ; 63 ; 1335-1352
2023-12-01
18 pages
Article (Journal)
Electronic Resource
English
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