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The catalytic properties of tungstated zirconia in n-heptane isomerization
Abstract The catalytic properties of zirconia modified with different amounts of tungstate anions in the hydroisomerization of n-heptane and its mixtures with benzene or toluene have been studied. It has been found that at a low temperature of 170°C, the yield of isoheptanes reaches 62.8% with a fairly high selectivity of 87.6% on the Pt/WO 4 2− /ZrO2 catalyst prepared by impregnation to contain 17.6 mol % tungstate anions. Under the same conditions, the yield of isoheptanes on a sulfated Pt/SO 4 2− /ZrO2 catalyst is as low as 14.0% with a selectivity of 20.3%. The hydroisomerization process effectively occurs on the tungstated catalyst in the presence of benzene or toluene.
The catalytic properties of tungstated zirconia in n-heptane isomerization
Abstract The catalytic properties of zirconia modified with different amounts of tungstate anions in the hydroisomerization of n-heptane and its mixtures with benzene or toluene have been studied. It has been found that at a low temperature of 170°C, the yield of isoheptanes reaches 62.8% with a fairly high selectivity of 87.6% on the Pt/WO 4 2− /ZrO2 catalyst prepared by impregnation to contain 17.6 mol % tungstate anions. Under the same conditions, the yield of isoheptanes on a sulfated Pt/SO 4 2− /ZrO2 catalyst is as low as 14.0% with a selectivity of 20.3%. The hydroisomerization process effectively occurs on the tungstated catalyst in the presence of benzene or toluene.
The catalytic properties of tungstated zirconia in n-heptane isomerization
Kuznetsova, L. I. (author) / Kazbanova, A. V. (author) / Kuznetsov, P. N. (author)
Petroleum Chemistry ; 52 ; 86-90
2012-03-01
5 pages
Article (Journal)
Electronic Resource
English
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