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    Palladium Nanoparticles in Hypercrosslinked Polystyrene: Synthesis and Application in the Hydrogenation of Arenes

    New search for: Lyubimov, S. E.
    New search for: Zvinchuk, A. A.
    New search for: Korlyukov, A. A.
    New search for: Davankov, V. A.
    New search for: Parenago, O. P.

    A novel method for incorporation of palladium nanoparticles into a porous hypercrosslinked polystyrene matrix has been developed. The composite obtained by reduction of [Pd(π-allyl)Cl]2 with hydrogen in supercritical CO2 shows high catalytic activity in the hydrogenation of benzene and can be used twelve (12) times in a row without any decrease in conversion rate. The catalyst is also suitable for quantitative hydrogenation of toluene, tetralin and phenol. The obtained catalytic system is compared with the palladium composite synthesized by a conventional method based on hypercrosslinked polystyrene.

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    Palladium Nanoparticles in Hypercrosslinked Polystyrene: Synthesis and Application in the Hydrogenation of Arenes

    New search for: Lyubimov, S. E.
    New search for: Zvinchuk, A. A.
    New search for: Korlyukov, A. A.
    New search for: Davankov, V. A.
    New search for: Parenago, O. P.

    A novel method for incorporation of palladium nanoparticles into a porous hypercrosslinked polystyrene matrix has been developed. The composite obtained by reduction of [Pd(π-allyl)Cl]2 with hydrogen in supercritical CO2 shows high catalytic activity in the hydrogenation of benzene and can be used twelve (12) times in a row without any decrease in conversion rate. The catalyst is also suitable for quantitative hydrogenation of toluene, tetralin and phenol. The obtained catalytic system is compared with the palladium composite synthesized by a conventional method based on hypercrosslinked polystyrene.

    Access

    Download

    Palladium Nanoparticles in Hypercrosslinked Polystyrene: Synthesis and Application in the Hydrogenation of Arenes

    New search for: Lyubimov, S. E.
    New search for: Zvinchuk, A. A.
    New search for: Korlyukov, A. A.
    New search for: Davankov, V. A.
    New search for: Parenago, O. P.

    A novel method for incorporation of palladium nanoparticles into a porous hypercrosslinked polystyrene matrix has been developed. The composite obtained by reduction of [Pd(π-allyl)Cl]2 with hydrogen in supercritical CO2 shows high catalytic activity in the hydrogenation of benzene and can be used twelve (12) times in a row without any decrease in conversion rate. The catalyst is also suitable for quantitative hydrogenation of toluene, tetralin and phenol. The obtained catalytic system is compared with the palladium composite synthesized by a conventional method based on hypercrosslinked polystyrene.

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    Download

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    Title:

    Palladium Nanoparticles in Hypercrosslinked Polystyrene: Synthesis and Application in the Hydrogenation of Arenes

    Additional title:

    Pet. Chem.

    Contributors:

    Lyubimov, S. E. (author) / Zvinchuk, A. A. (author) / Korlyukov, A. A. (author) / Davankov, V. A. (author) / Parenago, O. P. (author)

    Published in:

    Petroleum Chemistry ; 61 ; 76-80

    Publication date:

    2021-01-01

    Size:

    5 pages

    ISSN:

    1555-6239 , 0965-5441

    DOI:

    https://doi.org/10.1134/S0965544121010084

    Type of media:

    Article (Journal)

    Type of material:

    Electronic Resource

    Language:

    English

    Keywords:

    hypercrosslinked polystyrene , palladium nanoparticles , hydrogenation , arenes Chemistry , Industrial Chemistry/Chemical Engineering , Chemistry and Materials Science

    Licence:

    http://creativecommons.org/licenses/by/4.0/

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