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Thio derivatives of cyclopentanone and cyclohexanone

Baeva, L. A. / Ulendeeva, A. D. / Arslanova, D. D. / Shitikova, O. V. / Galkin, E. G. / Lyapina, N. K.

Abstract Mono-and bis(methylthiomethyl) substituted derivatives of cyclopentanone and cyclohexanone were obtained on the basis of natural methylmercaptan via the alkylthiomethylation of ketones, and these derivatives were converted into the corresponding γ-hydroxysulfides and ketosulfones via reduction with sodium borohydride and oxidation with hydrogen peroxide, respectively.

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Thio derivatives of cyclopentanone and cyclohexanone

Baeva, L. A. / Ulendeeva, A. D. / Arslanova, D. D. / Shitikova, O. V. / Galkin, E. G. / Lyapina, N. K.

Abstract Mono-and bis(methylthiomethyl) substituted derivatives of cyclopentanone and cyclohexanone were obtained on the basis of natural methylmercaptan via the alkylthiomethylation of ketones, and these derivatives were converted into the corresponding γ-hydroxysulfides and ketosulfones via reduction with sodium borohydride and oxidation with hydrogen peroxide, respectively.

Thio derivatives of cyclopentanone and cyclohexanone

Baeva, L. A. / Ulendeeva, A. D. / Arslanova, D. D. / Shitikova, O. V. / Galkin, E. G. / Lyapina, N. K.

Abstract Mono-and bis(methylthiomethyl) substituted derivatives of cyclopentanone and cyclohexanone were obtained on the basis of natural methylmercaptan via the alkylthiomethylation of ketones, and these derivatives were converted into the corresponding γ-hydroxysulfides and ketosulfones via reduction with sodium borohydride and oxidation with hydrogen peroxide, respectively.

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Title:

Thio derivatives of cyclopentanone and cyclohexanone

Contributors:

Baeva, L. A. (author) / Ulendeeva, A. D. (author) / Arslanova, D. D. (author) / Shitikova, O. V. (author) / Galkin, E. G. (author) / Lyapina, N. K. (author)

Published in:

Petroleum Chemistry ; 48 ; 393-397

Publication date:

2008-09-01

Size:

5 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544108050101

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Cyclohexanone , Petroleum Chemistry , Cyclopentanone , Dimethyl Phenyl , Phenyl Methyl Silicone Chemistry , Industrial Chemistry/Chemical Engineering

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