Carboxylation of <Emphasis Type="Italic">o</Emphasis>-, <Emphasis Type="Italic">m</Emphasis>-, and <Emphasis Type="Italic">p</Emphasis>-chlorophenols with sodium ethyl carbonate: Fid-Bau Portal

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Carboxylation of o-, m-, and p-chlorophenols with sodium ethyl carbonate

Suerbaev, Kh. A. / Chepaikin, E. G. / Kudaibergenov, N. Zh.

Abstract The possibility for the synthesis of 5-chloro-2-hydroxybenzoic, 4-chloro-2-hydroxybenzoic, and 3-chloro-2-hydroxybenzoic acids via regioselective carboxylation of p-, m-, and o-chlorophenols, respectively, with sodium ethyl carbonate has been demonstrated. Simple and convenient procedures developed in this study for the synthesis of chlorohydroxybenzoic acids can be used for their preparative and industrial synthesis.

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Carboxylation of o-, m-, and p-chlorophenols with sodium ethyl carbonate

Suerbaev, Kh. A. / Chepaikin, E. G. / Kudaibergenov, N. Zh.

Abstract The possibility for the synthesis of 5-chloro-2-hydroxybenzoic, 4-chloro-2-hydroxybenzoic, and 3-chloro-2-hydroxybenzoic acids via regioselective carboxylation of p-, m-, and o-chlorophenols, respectively, with sodium ethyl carbonate has been demonstrated. Simple and convenient procedures developed in this study for the synthesis of chlorohydroxybenzoic acids can be used for their preparative and industrial synthesis.

Carboxylation of o-, m-, and p-chlorophenols with sodium ethyl carbonate

Suerbaev, Kh. A. / Chepaikin, E. G. / Kudaibergenov, N. Zh.

Abstract The possibility for the synthesis of 5-chloro-2-hydroxybenzoic, 4-chloro-2-hydroxybenzoic, and 3-chloro-2-hydroxybenzoic acids via regioselective carboxylation of p-, m-, and o-chlorophenols, respectively, with sodium ethyl carbonate has been demonstrated. Simple and convenient procedures developed in this study for the synthesis of chlorohydroxybenzoic acids can be used for their preparative and industrial synthesis.

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Title:

Carboxylation of o-, m-, and p-chlorophenols with sodium ethyl carbonate

Contributors:

Suerbaev, Kh. A. (author) / Chepaikin, E. G. (author) / Kudaibergenov, N. Zh. (author)

Published in:

Petroleum Chemistry ; 57 ; 436-440

Publication date:

2017-05-01

Size:

5 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544117050103

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

chlorophenolcarboxylic acids , chlorophenols , sodium ethyl carbonate , carboxylation Chemistry , Industrial Chemistry/Chemical Engineering

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