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Dissociation energies of N-H bonds in aromatic amines (review)

Denisov, E. T. / Denisova, T. G.

Abstract The review discusses compiled data on the N-H bond dissociation energies of 108 aromatic amines of various structures. A brief description of experimental methods for their determination has been given, and the results obtained by different methods have been compared. Stabilization energies of structurally different aminyl radicals (ΔE RS) have been calculated, and this structural energy has been compared with ΔE RS of phenylaminyl and phenoxyl radicals. Values of D N-H, D O-H, and D S-H for a series of hybrid antioxidants (19 compounds) are reported. Bibliography: 42 references.

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Dissociation energies of N-H bonds in aromatic amines (review)

Denisov, E. T. / Denisova, T. G.

Abstract The review discusses compiled data on the N-H bond dissociation energies of 108 aromatic amines of various structures. A brief description of experimental methods for their determination has been given, and the results obtained by different methods have been compared. Stabilization energies of structurally different aminyl radicals (ΔE RS) have been calculated, and this structural energy has been compared with ΔE RS of phenylaminyl and phenoxyl radicals. Values of D N-H, D O-H, and D S-H for a series of hybrid antioxidants (19 compounds) are reported. Bibliography: 42 references.

Dissociation energies of N-H bonds in aromatic amines (review)

Denisov, E. T. / Denisova, T. G.

Abstract The review discusses compiled data on the N-H bond dissociation energies of 108 aromatic amines of various structures. A brief description of experimental methods for their determination has been given, and the results obtained by different methods have been compared. Stabilization energies of structurally different aminyl radicals (ΔE RS) have been calculated, and this structural energy has been compared with ΔE RS of phenylaminyl and phenoxyl radicals. Values of D N-H, D O-H, and D S-H for a series of hybrid antioxidants (19 compounds) are reported. Bibliography: 42 references.

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Title:

Dissociation energies of N-H bonds in aromatic amines (review)

Contributors:

Denisov, E. T. (author) / Denisova, T. G. (author)

Published in:

Petroleum Chemistry ; 55 ; 85-103

Publication date:

2015-03-01

Size:

19 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544115020073

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

aromatic amines , hybrid antioxidants , correlation equations , N-H bond dissociation energy , radical stabilization energy Chemistry , Industrial Chemistry/Chemical Engineering

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