Ethylene oligomerization mediated by iron formazanates and organoaluminum compounds: Fid-Bau Portal

Ethylene oligomerization mediated by iron formazanates and organoaluminum compounds

Pavlova, I. S. / Pervova, I. G. / Belov, G. P. / Khasbiullin, I. I. / Slepukhin, P. A.

Abstract A number of iron(II) complexes have been synthesized on the basis of benzothiazolylformazans, and their structure and composition have been characterized by elemental analysis, mass spectrometry, and X-ray analysis. The catalytic behavior of Fe(II) formazanates in the reaction of ethylene oligomerization in the presence of various organoaluminum compounds has been studied. Methylaluminoxane facilitates the formation of α-olefins (butene-1, hexene-1) and the byproducts hexene isomers; ethylaluminum dichloride (AlC2H5Cl2) increases the selectivity for alkyltoluenes.

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Ethylene oligomerization mediated by iron formazanates and organoaluminum compounds

Pavlova, I. S. / Pervova, I. G. / Belov, G. P. / Khasbiullin, I. I. / Slepukhin, P. A.

Abstract

Ethylene oligomerization mediated by iron formazanates and organoaluminum compounds

Pavlova, I. S. / Pervova, I. G. / Belov, G. P. / Khasbiullin, I. I. / Slepukhin, P. A.

Abstract

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Title:

Ethylene oligomerization mediated by iron formazanates and organoaluminum compounds

Contributors:

Pavlova, I. S. (author) / Pervova, I. G. (author) / Belov, G. P. (author) / Khasbiullin, I. I. (author) / Slepukhin, P. A. (author)

Published in:

Petroleum Chemistry ; 53 ; 127-133

Publication date:

2013-03-01

Size:

7 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544113020072

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

oligomerization , ethylene , organoaluminum compounds , iron formazanates Chemistry , Industrial Chemistry/Chemical Engineering

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