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    Heterogeneous catalysis in ionic liquids: The heck reaction of bromobenzene with styrene over palladium supported on mesoporous carbon

    New search for: Aslanov, L. A.
    New search for: Valetskii, P. M.
    New search for: Zakharov, V. N.
    New search for: Kabachii, Yu. A.
    New search for: Kochev, S. Yu.
    New search for: Romanovskii, B. V.
    New search for: Yatsenko, A. V.

    Abstract Tributylhexylammonium bistriflamide [(C4H9)(C6H13)N][(CF3SO2)2N], an ionic liquid, was used as a solvent for the Heck reaction of bromobenzene with styrene in the presence of Pd deposited onto a mesoporous carbon support. It was found that dibutylamine used as a basic reagent to scavenge hydrogen bromide results in higher conversions of the reactants and higher yields of stilbene than sodium acetate. It was shown that the IL is fully recoverable after use in the catalytic reaction.

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    Heterogeneous catalysis in ionic liquids: The heck reaction of bromobenzene with styrene over palladium supported on mesoporous carbon

    New search for: Aslanov, L. A.
    New search for: Valetskii, P. M.
    New search for: Zakharov, V. N.
    New search for: Kabachii, Yu. A.
    New search for: Kochev, S. Yu.
    New search for: Romanovskii, B. V.
    New search for: Yatsenko, A. V.

    Abstract Tributylhexylammonium bistriflamide [(C4H9)(C6H13)N][(CF3SO2)2N], an ionic liquid, was used as a solvent for the Heck reaction of bromobenzene with styrene in the presence of Pd deposited onto a mesoporous carbon support. It was found that dibutylamine used as a basic reagent to scavenge hydrogen bromide results in higher conversions of the reactants and higher yields of stilbene than sodium acetate. It was shown that the IL is fully recoverable after use in the catalytic reaction.

    Access

    Check access
    Check availability in my library
    Order at Subito €

    Heterogeneous catalysis in ionic liquids: The heck reaction of bromobenzene with styrene over palladium supported on mesoporous carbon

    New search for: Aslanov, L. A.
    New search for: Valetskii, P. M.
    New search for: Zakharov, V. N.
    New search for: Kabachii, Yu. A.
    New search for: Kochev, S. Yu.
    New search for: Romanovskii, B. V.
    New search for: Yatsenko, A. V.

    Abstract Tributylhexylammonium bistriflamide [(C4H9)(C6H13)N][(CF3SO2)2N], an ionic liquid, was used as a solvent for the Heck reaction of bromobenzene with styrene in the presence of Pd deposited onto a mesoporous carbon support. It was found that dibutylamine used as a basic reagent to scavenge hydrogen bromide results in higher conversions of the reactants and higher yields of stilbene than sodium acetate. It was shown that the IL is fully recoverable after use in the catalytic reaction.

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    Title:

    Heterogeneous catalysis in ionic liquids: The heck reaction of bromobenzene with styrene over palladium supported on mesoporous carbon

    Contributors:

    Aslanov, L. A. (author) / Valetskii, P. M. (author) / Zakharov, V. N. (author) / Kabachii, Yu. A. (author) / Kochev, S. Yu. (author) / Romanovskii, B. V. (author) / Yatsenko, A. V. (author)

    Published in:

    Petroleum Chemistry ; 48 ; 360-365

    Publication date:

    2008-09-01

    Size:

    6 pages

    ISSN:

    1555-6239 , 0965-5441

    DOI:

    https://doi.org/10.1134/S0965544108050058

    Type of media:

    Article (Journal)

    Type of material:

    Electronic Resource

    Language:

    English

    Keywords:

    Ionic Liquid , Styrene , Stilbene , Petroleum Chemistry , Mesoporous Carbon Chemistry , Industrial Chemistry/Chemical Engineering

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