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Palladium-containing nanodiamonds in hydrogenation and hydroamination

Magdalinova, N. A. / Kalmykov, P. A. / Klyuev, M. V.

Abstract Palladium catalysts in the form of Pd nanoparticles supported on nanodiamonds have been studied in the hydrogenation of nitrobenzene, allyl alcohol, and cyclohexene and in the hydrogenating amination of propanal with 4-aminobenzoic acid. The ratio of two valence states of palladium, i.e., Pd2+ and Pd0, in the catalysts has been determined by XPS. The dependence of hydrogenation reaction rate on electron density at the reaction site of nitrobenzene, allyl alcohol, cyclohexene, and 4-(propylideneamino)benzoic acid molecules has been studied using quantum chemical calculations (HF/6-31G, PCM).

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Palladium-containing nanodiamonds in hydrogenation and hydroamination

Magdalinova, N. A. / Kalmykov, P. A. / Klyuev, M. V.

Abstract Palladium catalysts in the form of Pd nanoparticles supported on nanodiamonds have been studied in the hydrogenation of nitrobenzene, allyl alcohol, and cyclohexene and in the hydrogenating amination of propanal with 4-aminobenzoic acid. The ratio of two valence states of palladium, i.e., Pd2+ and Pd0, in the catalysts has been determined by XPS. The dependence of hydrogenation reaction rate on electron density at the reaction site of nitrobenzene, allyl alcohol, cyclohexene, and 4-(propylideneamino)benzoic acid molecules has been studied using quantum chemical calculations (HF/6-31G, PCM).

Palladium-containing nanodiamonds in hydrogenation and hydroamination

Magdalinova, N. A. / Kalmykov, P. A. / Klyuev, M. V.

Abstract Palladium catalysts in the form of Pd nanoparticles supported on nanodiamonds have been studied in the hydrogenation of nitrobenzene, allyl alcohol, and cyclohexene and in the hydrogenating amination of propanal with 4-aminobenzoic acid. The ratio of two valence states of palladium, i.e., Pd2+ and Pd0, in the catalysts has been determined by XPS. The dependence of hydrogenation reaction rate on electron density at the reaction site of nitrobenzene, allyl alcohol, cyclohexene, and 4-(propylideneamino)benzoic acid molecules has been studied using quantum chemical calculations (HF/6-31G, PCM).

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Title:

Palladium-containing nanodiamonds in hydrogenation and hydroamination

Contributors:

Magdalinova, N. A. (author) / Kalmykov, P. A. (author) / Klyuev, M. V. (author)

Published in:

Petroleum Chemistry ; 52 ; 299-304

Publication date:

2012-09-01

Size:

6 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544112050064

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Palladium , Fullerene , Nitrobenzene , Petroleum Chemistry , Allyl Alcohol Chemistry , Industrial Chemistry/Chemical Engineering

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