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Effect of solvent nature on the catalytic hydroformylation of 2,3-dihydrofuran

Wol’f, E. Yu. / Vartanyan, M. M. / Lapidus, A. L.

Abstract The effect of the solvent nature on the process of hydroformylation of 2,3-dihydrofuran in the presence of the phosphine-containing, complex Rh catalyst HRh(CO)(PPh3)3 has been studied. The influence of solvent polarity and basicity on the conversion of 2,3-dihydrofuran has been revealed, and the composition of tetrahydrofuran aldehydes and the selectivity of their formation have been determined.

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Effect of solvent nature on the catalytic hydroformylation of 2,3-dihydrofuran

Wol’f, E. Yu. / Vartanyan, M. M. / Lapidus, A. L.

Abstract The effect of the solvent nature on the process of hydroformylation of 2,3-dihydrofuran in the presence of the phosphine-containing, complex Rh catalyst HRh(CO)(PPh3)3 has been studied. The influence of solvent polarity and basicity on the conversion of 2,3-dihydrofuran has been revealed, and the composition of tetrahydrofuran aldehydes and the selectivity of their formation have been determined.

Effect of solvent nature on the catalytic hydroformylation of 2,3-dihydrofuran

Wol’f, E. Yu. / Vartanyan, M. M. / Lapidus, A. L.

Abstract The effect of the solvent nature on the process of hydroformylation of 2,3-dihydrofuran in the presence of the phosphine-containing, complex Rh catalyst HRh(CO)(PPh3)3 has been studied. The influence of solvent polarity and basicity on the conversion of 2,3-dihydrofuran has been revealed, and the composition of tetrahydrofuran aldehydes and the selectivity of their formation have been determined.

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Title:

Effect of solvent nature on the catalytic hydroformylation of 2,3-dihydrofuran

Contributors:

Wol’f, E. Yu. (author) / Vartanyan, M. M. (author) / Lapidus, A. L. (author)

Published in:

Petroleum Chemistry ; 53 ; 194-196

Publication date:

2013-05-01

Size:

3 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544113030134

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

hydroformylation , 2,3-dihydrofuran , phosphine-containing complex , rhodium catalysts , 2-formyltetrahydrofuran , 3-formyltetrahydrofuran Chemistry , Industrial Chemistry/Chemical Engineering

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