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Hydroconversion of Vacuum Residue of a Blend of Western Siberian Oils in the Presence of Ex Situ Synthesized Suspensions of Nanosized Catalysts
Concentrated suspensions of nanosized МоS2, МоS2+Ni7S6, Ni7S6, Fe1– xS, and (NH4)0.25 · WO3 particles with an average size of 273–364 nm have been synthesized from reverse emulsions of aqueous solutions of molybdenum, nickel, iron, and tungsten salts in the presence of a sulfiding agent and hydrogen in oil vacuum distillation residues and tested in oil vacuum distillation residue hydroconversion running in an autoclave and a pilot flow system. The test results have shown that the highest activity in hydrogenolysis reactions is exhibited by Mo-containing catalysts. The kinetic characteristics have been determined; the heat of the hydroconversion process has been calculated.
Hydroconversion of Vacuum Residue of a Blend of Western Siberian Oils in the Presence of Ex Situ Synthesized Suspensions of Nanosized Catalysts
Concentrated suspensions of nanosized МоS2, МоS2+Ni7S6, Ni7S6, Fe1– xS, and (NH4)0.25 · WO3 particles with an average size of 273–364 nm have been synthesized from reverse emulsions of aqueous solutions of molybdenum, nickel, iron, and tungsten salts in the presence of a sulfiding agent and hydrogen in oil vacuum distillation residues and tested in oil vacuum distillation residue hydroconversion running in an autoclave and a pilot flow system. The test results have shown that the highest activity in hydrogenolysis reactions is exhibited by Mo-containing catalysts. The kinetic characteristics have been determined; the heat of the hydroconversion process has been calculated.
Hydroconversion of Vacuum Residue of a Blend of Western Siberian Oils in the Presence of Ex Situ Synthesized Suspensions of Nanosized Catalysts
Pet. Chem.
Kadiev, Kh. M. (author) / Gyul’maliev, A. M. (author) / Zekel’, L. A. (author) / Kadieva, M. Kh. (author) / Dandaev, A. U. (author) / Batov, A. E. (author) / Visaliev, M. Ya. (author)
Petroleum Chemistry ; 59 ; S37-S44
2019-12-01
Article (Journal)
Electronic Resource
English