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Influence of zeolite type on activity of Fischer-Tropsch iron catalysts

Vytnova, L. A. / Bogolepova, E. I. / Shuikin, A. N. / Kurkin, V. I. / Marchevskaya, E. V. / Kliger, G. A.

Abstract The influence of zeolite type on the product composition, activity, and stability of a binary Fischer-Tropsch iron-containing catalyst was studied. It was shown that the redistribution of acid sites takes place during zeolite shaping with alumina, and, as a result, the relative amount of strong acid sites decreases and the proportion of medium-strength acid sites increases. Zeolites ZSM-5 and ZSM-12 appeared to be the most active in secondary reactions of hydrocarbon conversion under the conditions of hydrocarbon synthesis from CO and H2.

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Influence of zeolite type on activity of Fischer-Tropsch iron catalysts

Vytnova, L. A. / Bogolepova, E. I. / Shuikin, A. N. / Kurkin, V. I. / Marchevskaya, E. V. / Kliger, G. A.

Abstract The influence of zeolite type on the product composition, activity, and stability of a binary Fischer-Tropsch iron-containing catalyst was studied. It was shown that the redistribution of acid sites takes place during zeolite shaping with alumina, and, as a result, the relative amount of strong acid sites decreases and the proportion of medium-strength acid sites increases. Zeolites ZSM-5 and ZSM-12 appeared to be the most active in secondary reactions of hydrocarbon conversion under the conditions of hydrocarbon synthesis from CO and H2.

Influence of zeolite type on activity of Fischer-Tropsch iron catalysts

Vytnova, L. A. / Bogolepova, E. I. / Shuikin, A. N. / Kurkin, V. I. / Marchevskaya, E. V. / Kliger, G. A.

Abstract The influence of zeolite type on the product composition, activity, and stability of a binary Fischer-Tropsch iron-containing catalyst was studied. It was shown that the redistribution of acid sites takes place during zeolite shaping with alumina, and, as a result, the relative amount of strong acid sites decreases and the proportion of medium-strength acid sites increases. Zeolites ZSM-5 and ZSM-12 appeared to be the most active in secondary reactions of hydrocarbon conversion under the conditions of hydrocarbon synthesis from CO and H2.

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Title:

Influence of zeolite type on activity of Fischer-Tropsch iron catalysts

Contributors:

Vytnova, L. A. (author) / Bogolepova, E. I. (author) / Shuikin, A. N. (author) / Kurkin, V. I. (author) / Marchevskaya, E. V. (author) / Kliger, G. A. (author)

Published in:

Petroleum Chemistry ; 46 ; 324-331

Publication date:

2006-10-01

Size:

8 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S0965544106050045

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Zeolite , Acid Site , Petroleum Chemistry , Strong Acid Site , Tropsch Synthesis Chemistry , Industrial Chemistry/Chemical Engineering

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