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Copolymerization of 5-(trimethylsilyl)norbornene and 5-ethylidene-2-norbornene

Bulgakov, B. A. / Bermeshev, M. V. / Gringol’ts, M. L. / Filatova, M. P. / Finkel’shtein, E. Sh.

Abstract Addition and metathesis copolymerization of 5-(trimethylsilyl)norbornene (TMSNB) and 5-ethylidene-2-norbornene (ENB) has been studied. High-molecular-weight metathesis copolymers have been obtained on the first-generation Grubbs catalyst based on the Ru carbene complex Cl2Ru(=CHPh)(PCy3)2 with nearly quantitative yields. Addition copolymerization has been carried out on the Ni(II) naphthenatemethylaluminoxane (MAO) catalytic system. In both cases copolymerization proceeded without participation of ethylidene double bond. Copolymers of this type are promising ones for manufacturing stable highly permeable polymeric membranes, since they are capable for crosslinking.

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Copolymerization of 5-(trimethylsilyl)norbornene and 5-ethylidene-2-norbornene

Bulgakov, B. A. / Bermeshev, M. V. / Gringol’ts, M. L. / Filatova, M. P. / Finkel’shtein, E. Sh.

Abstract Addition and metathesis copolymerization of 5-(trimethylsilyl)norbornene (TMSNB) and 5-ethylidene-2-norbornene (ENB) has been studied. High-molecular-weight metathesis copolymers have been obtained on the first-generation Grubbs catalyst based on the Ru carbene complex Cl2Ru(=CHPh)(PCy3)2 with nearly quantitative yields. Addition copolymerization has been carried out on the Ni(II) naphthenatemethylaluminoxane (MAO) catalytic system. In both cases copolymerization proceeded without participation of ethylidene double bond. Copolymers of this type are promising ones for manufacturing stable highly permeable polymeric membranes, since they are capable for crosslinking.

Copolymerization of 5-(trimethylsilyl)norbornene and 5-ethylidene-2-norbornene

Bulgakov, B. A. / Bermeshev, M. V. / Gringol’ts, M. L. / Filatova, M. P. / Finkel’shtein, E. Sh.

Abstract Addition and metathesis copolymerization of 5-(trimethylsilyl)norbornene (TMSNB) and 5-ethylidene-2-norbornene (ENB) has been studied. High-molecular-weight metathesis copolymers have been obtained on the first-generation Grubbs catalyst based on the Ru carbene complex Cl2Ru(=CHPh)(PCy3)2 with nearly quantitative yields. Addition copolymerization has been carried out on the Ni(II) naphthenatemethylaluminoxane (MAO) catalytic system. In both cases copolymerization proceeded without participation of ethylidene double bond. Copolymers of this type are promising ones for manufacturing stable highly permeable polymeric membranes, since they are capable for crosslinking.

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Title:

Copolymerization of 5-(trimethylsilyl)norbornene and 5-ethylidene-2-norbornene

Contributors:

Bulgakov, B. A. (author) / Bermeshev, M. V. (author) / Gringol’ts, M. L. (author) / Filatova, M. P. (author) / Finkel’shtein, E. Sh. (author)

Published in:

Petroleum Chemistry ; 52 ; 119-122

Publication date:

2012-03-01

Size:

4 pages

ISSN:

1555-6239 , 0965-5441

DOI:

https://doi.org/10.1134/S096554411202003X

Type of media:

Article (Journal)

Type of material:

Electronic Resource

Language:

English

Keywords:

Copolymerization , Trimethylsilyl , Petroleum Chemistry , Metathesis , Ethylidene Chemistry , Industrial Chemistry/Chemical Engineering

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