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The mechanism for soluble phosphates to improve the water resistance of magnesium oxychloride cement
This paper discusses the reasons why the addition of some soluble phosphates to magnesium oxychloride cement (MOC) can greatly improve its water resistance. With the XRD analysis and the determination of the strength retention coefficients (a judging index for the water resistance), it has been shown that the addition of small quantity of the soluble phosphates, such as H3PO4, NaH2PO4 dot 2H 2O, and NH4H2PO4, to MOC pastes does not influence the phases formed in the MOC pastes, but can result in the great increases of the strength retention coefficients of hardened MOC pastes, i.e., the great improvement of the water resistance of MOC. It was considered that the key components being responsible for the improvement of the water resistance could be the anions H2PO4 -, HPO 42-, and PO43- yielded by the ionization of these phosphates in the solution of MOC pastes. These anions can decrease the lowest concentration of Mg2+ ions in the solution required by the formation of 5Mg(OH)2 dot MgCl 2 dot 8H2O (5-phase) or 3Mg(OH) 2 dot MgCl2 dot 8H2O (3-phase) in the MOC pastes and increase the stability of these phases in water. Thus, when the hardened MOC pastes with small quantity of the soluble phosphates are immersed in water, the 5-phase or 3-phase in them will not be decomposed by water, which makes the strength of the hardened MOC pastes remain unchanged in water.
The mechanism for soluble phosphates to improve the water resistance of magnesium oxychloride cement
This paper discusses the reasons why the addition of some soluble phosphates to magnesium oxychloride cement (MOC) can greatly improve its water resistance. With the XRD analysis and the determination of the strength retention coefficients (a judging index for the water resistance), it has been shown that the addition of small quantity of the soluble phosphates, such as H3PO4, NaH2PO4 dot 2H 2O, and NH4H2PO4, to MOC pastes does not influence the phases formed in the MOC pastes, but can result in the great increases of the strength retention coefficients of hardened MOC pastes, i.e., the great improvement of the water resistance of MOC. It was considered that the key components being responsible for the improvement of the water resistance could be the anions H2PO4 -, HPO 42-, and PO43- yielded by the ionization of these phosphates in the solution of MOC pastes. These anions can decrease the lowest concentration of Mg2+ ions in the solution required by the formation of 5Mg(OH)2 dot MgCl 2 dot 8H2O (5-phase) or 3Mg(OH) 2 dot MgCl2 dot 8H2O (3-phase) in the MOC pastes and increase the stability of these phases in water. Thus, when the hardened MOC pastes with small quantity of the soluble phosphates are immersed in water, the 5-phase or 3-phase in them will not be decomposed by water, which makes the strength of the hardened MOC pastes remain unchanged in water.
The mechanism for soluble phosphates to improve the water resistance of magnesium oxychloride cement
Deng, Dehua (author)
Cement and Concrete Research ; 33 ; 1311-1317
2003
7 Seiten, 6 Quellen
Article (Journal)
English
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