A platform for research: civil engineering, architecture and urbanism
A platform for research: civil engineering, architecture and urbanism
The coexistence of geopolymeric gel and calcium silicate hydrate at the early stage of alkaline activation
Scanning electron microscopy was used to study the effects of the addition of ground granulated blast furnace slag (GGBFS) on the microstructure and mechanical properties of metakaolin (MK) based geopolymers. It was found that it is possible to have geopolymeric gel and calcium silicate hydrate (CSH) gel forming simultaneously within a single binder. The coexistence of these two phases is dependent on the alkalinity of the alkali activator and the MK / GGBFS mass ratio. It has been found that the formation of CSH gel together with the geopolymeric gel occurs only in a system at low alkalinity. In the presence of high concentrations of NaOH (> 7.5 M), the geopolymeric gel is the predominant phase formed with small calcium precipitates scattered within the binder. The coexistence of the two phases is not observed unless a substantial amount of a reactive calcium source is present initially. It is thought that voids and pores within the geopolymeric binder become filled with the CSH gel. This helps to bridge the gaps between the different hydrated phases and unreacted particles; thereby resulting in the observed increase in mechanical strength for these binders.
The coexistence of geopolymeric gel and calcium silicate hydrate at the early stage of alkaline activation
Scanning electron microscopy was used to study the effects of the addition of ground granulated blast furnace slag (GGBFS) on the microstructure and mechanical properties of metakaolin (MK) based geopolymers. It was found that it is possible to have geopolymeric gel and calcium silicate hydrate (CSH) gel forming simultaneously within a single binder. The coexistence of these two phases is dependent on the alkalinity of the alkali activator and the MK / GGBFS mass ratio. It has been found that the formation of CSH gel together with the geopolymeric gel occurs only in a system at low alkalinity. In the presence of high concentrations of NaOH (> 7.5 M), the geopolymeric gel is the predominant phase formed with small calcium precipitates scattered within the binder. The coexistence of the two phases is not observed unless a substantial amount of a reactive calcium source is present initially. It is thought that voids and pores within the geopolymeric binder become filled with the CSH gel. This helps to bridge the gaps between the different hydrated phases and unreacted particles; thereby resulting in the observed increase in mechanical strength for these binders.
The coexistence of geopolymeric gel and calcium silicate hydrate at the early stage of alkaline activation
Yip, C.K. (author) / Lukey, G.C. (author) / Van Deventer, J.S.J. (author)
Cement and Concrete Research ; 35 ; 1688-1697
2005
10 Seiten, 30 Quellen
Article (Journal)
English
| British Library Online Contents | 2005
Microanalysis of calcium silicate hydrate gel formed within a geopolymeric binder
| Tema Archive | 2003
Microanalysis of calcium silicate hydrate gel formed within a geopolymeric binder
| British Library Online Contents | 2003
| British Library Online Contents | 2009