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Stabilization of High‐Pressure Phase of Face‐Centered Cubic Lutetium Trihydride at Ambient Conditions
https://orcid.org/0000-0002-9613-2221
https://orcid.org/0000-0001-9513-0147
https://orcid.org/0000-0002-9664-848X
AbstractSuperconductivity at room temperature and near‐ambient pressures is a highly sought‐after phenomenon in physics and materials science. A recent study reported the presence of this phenomenon in N‐doped lutetium hydride [Nature 615, 244 (2023)], however, subsequent experimental and theoretical investigations have yielded inconsistent results. This study undertakes a systematic examination of synthesis methods involving high temperatures and pressures, leading to insights into the impact of the reaction path on the products and the construction of a phase diagram for lutetium hydrides. Notably, the high‐pressure phase of face‐centered cubic LuH3 (fcc‐LuH3) is maintained to ambient conditions through a high‐temperature and high‐pressure method. Based on temperature and anharmonic effects corrections, the lattice dynamic calculations demonstrate the stability of fcc‐LuH3 at ambient conditions. However, no superconductivity is observed above 2 K in resistance and magnetization measurements in fcc‐LuH3 at ambient pressure. This work establishes a comprehensive synthesis approach for lutetium hydrides, thereby enhancing the understanding of the high‐temperature and high‐pressure method employed in hydrides with superconductivity deeply.
Stabilization of High‐Pressure Phase of Face‐Centered Cubic Lutetium Trihydride at Ambient Conditions
https://orcid.org/0000-0002-9613-2221
https://orcid.org/0000-0001-9513-0147
https://orcid.org/0000-0002-9664-848X
AbstractSuperconductivity at room temperature and near‐ambient pressures is a highly sought‐after phenomenon in physics and materials science. A recent study reported the presence of this phenomenon in N‐doped lutetium hydride [Nature 615, 244 (2023)], however, subsequent experimental and theoretical investigations have yielded inconsistent results. This study undertakes a systematic examination of synthesis methods involving high temperatures and pressures, leading to insights into the impact of the reaction path on the products and the construction of a phase diagram for lutetium hydrides. Notably, the high‐pressure phase of face‐centered cubic LuH3 (fcc‐LuH3) is maintained to ambient conditions through a high‐temperature and high‐pressure method. Based on temperature and anharmonic effects corrections, the lattice dynamic calculations demonstrate the stability of fcc‐LuH3 at ambient conditions. However, no superconductivity is observed above 2 K in resistance and magnetization measurements in fcc‐LuH3 at ambient pressure. This work establishes a comprehensive synthesis approach for lutetium hydrides, thereby enhancing the understanding of the high‐temperature and high‐pressure method employed in hydrides with superconductivity deeply.
Stabilization of High‐Pressure Phase of Face‐Centered Cubic Lutetium Trihydride at Ambient Conditions
https://orcid.org/0000-0002-9613-2221
https://orcid.org/0000-0001-9513-0147
https://orcid.org/0000-0002-9664-848X
AbstractSuperconductivity at room temperature and near‐ambient pressures is a highly sought‐after phenomenon in physics and materials science. A recent study reported the presence of this phenomenon in N‐doped lutetium hydride [Nature 615, 244 (2023)], however, subsequent experimental and theoretical investigations have yielded inconsistent results. This study undertakes a systematic examination of synthesis methods involving high temperatures and pressures, leading to insights into the impact of the reaction path on the products and the construction of a phase diagram for lutetium hydrides. Notably, the high‐pressure phase of face‐centered cubic LuH3 (fcc‐LuH3) is maintained to ambient conditions through a high‐temperature and high‐pressure method. Based on temperature and anharmonic effects corrections, the lattice dynamic calculations demonstrate the stability of fcc‐LuH3 at ambient conditions. However, no superconductivity is observed above 2 K in resistance and magnetization measurements in fcc‐LuH3 at ambient pressure. This work establishes a comprehensive synthesis approach for lutetium hydrides, thereby enhancing the understanding of the high‐temperature and high‐pressure method employed in hydrides with superconductivity deeply.
Stabilization of High‐Pressure Phase of Face‐Centered Cubic Lutetium Trihydride at Ambient Conditions
Advanced Science
Li, Xin (author) / Wang, Ying (author) / Fu, Yuhao (author) / Redfern, Simon A. T. (author) / Jiang, Shuqing (author) / Zhu, Pinwen (author) / Cui, Tian (author)
Advanced Science ; 11
2024-08-01
Article (Journal)
Electronic Resource
English
| Wiley | 2024
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