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Donor–Acceptor Viologens with Through‐Space Conjugation for Enhanced Visible‐Light‐Driven Photocatalysis
https://orcid.org/0000-0003-4669-8347
https://orcid.org/0000-0002-5319-7084
AbstractA series of novel donor–acceptor (D–A) type viologens with through‐space conjugation (TSC) are synthesized. The synergistic effect of D–A conjugation and TSC endow these compounds with a narrower energy gap, excellent redox properties, strong absorption in the visible range (up to 450 nm), and high efficiency of intramolecular charge transfer (ICT). These compounds also exhibit a long‐lived charge separation state and stable radical formation. Considering their impressive photophysical and redox properties, TSC viologens with D–A conjugation are explored for visible‐light‐driven photocatalysis. As a catalyst in oxidative coupling reactions under visible light, compound 9 can achieve a yield of 94%, attributed to its strong ICT effect. Additionally, hybridized into graphitic carbon nitride (g‐C₃N₄), compound 9 enhances hydrogen production performance under visible light, achieving an H2 generation rate of 4102 µmol h−1g−1. This study highlights the potential applications of TSC viologens in photocatalytic systems.
Donor–Acceptor Viologens with Through‐Space Conjugation for Enhanced Visible‐Light‐Driven Photocatalysis
https://orcid.org/0000-0003-4669-8347
https://orcid.org/0000-0002-5319-7084
AbstractA series of novel donor–acceptor (D–A) type viologens with through‐space conjugation (TSC) are synthesized. The synergistic effect of D–A conjugation and TSC endow these compounds with a narrower energy gap, excellent redox properties, strong absorption in the visible range (up to 450 nm), and high efficiency of intramolecular charge transfer (ICT). These compounds also exhibit a long‐lived charge separation state and stable radical formation. Considering their impressive photophysical and redox properties, TSC viologens with D–A conjugation are explored for visible‐light‐driven photocatalysis. As a catalyst in oxidative coupling reactions under visible light, compound 9 can achieve a yield of 94%, attributed to its strong ICT effect. Additionally, hybridized into graphitic carbon nitride (g‐C₃N₄), compound 9 enhances hydrogen production performance under visible light, achieving an H2 generation rate of 4102 µmol h−1g−1. This study highlights the potential applications of TSC viologens in photocatalytic systems.
Donor–Acceptor Viologens with Through‐Space Conjugation for Enhanced Visible‐Light‐Driven Photocatalysis
https://orcid.org/0000-0003-4669-8347
https://orcid.org/0000-0002-5319-7084
AbstractA series of novel donor–acceptor (D–A) type viologens with through‐space conjugation (TSC) are synthesized. The synergistic effect of D–A conjugation and TSC endow these compounds with a narrower energy gap, excellent redox properties, strong absorption in the visible range (up to 450 nm), and high efficiency of intramolecular charge transfer (ICT). These compounds also exhibit a long‐lived charge separation state and stable radical formation. Considering their impressive photophysical and redox properties, TSC viologens with D–A conjugation are explored for visible‐light‐driven photocatalysis. As a catalyst in oxidative coupling reactions under visible light, compound 9 can achieve a yield of 94%, attributed to its strong ICT effect. Additionally, hybridized into graphitic carbon nitride (g‐C₃N₄), compound 9 enhances hydrogen production performance under visible light, achieving an H2 generation rate of 4102 µmol h−1g−1. This study highlights the potential applications of TSC viologens in photocatalytic systems.
Donor–Acceptor Viologens with Through‐Space Conjugation for Enhanced Visible‐Light‐Driven Photocatalysis
Advanced Science
Qiao, Yi (author) / Xu, Liang (author) / Liu, Xiaoyang (author) / Gao, Yujing (author) / Li, Naiyao (author) / Li, Yawen (author) / Cao, Tianle (author) / Yan, Ni (author) / Liu, Zishun (author) / He, Gang (author)
Advanced Science ; 12
2025-01-01
Article (Journal)
Electronic Resource
English
| Wiley | 2025
| British Library Online Contents | 2019
| British Library Online Contents | 2018