Catalytic Reduction of Hexaminecobalt(III) by Pitch‐based Spherical Activated Carbon (PBSAC): Fid-Bau Portal

Catalytic Reduction of Hexaminecobalt(III) by Pitch‐based Spherical Activated Carbon (PBSAC)

Chen, Yu / Mao, Yan‐peng / Zhu, Hai‐song / Cheng, Jing‐yi / Long, Xiang‐li / Yuan, Wei‐kang

The wet ammonia (NH₃) desulfurization process can be retrofitted to remove nitric oxide (NO) and sulfur dioxide (SO₂) simultaneously by adding soluble cobalt(II) salt into the aqueous ammonia solution. Activated carbon is used as a catalyst to regenerate hexaminecobalt(II), Co(NH₃) $_{6}^{2+}$ , so that NO removal efficiency can be maintained at a high level for a long time. In this study, the catalytic performance of pitch‐based spherical activated carbon (PBSAC) in the simultaneous removal of NO and SO₂ with this wet ammonia scrubbing process has been studied systematically. Experiments have been performed in a batch stirred cell to test the catalytic characteristics of PBSAC in the catalytic reduction of hexaminecobalt(III), Co(NH₃) $_{6}^{3+}$ . The experimental results show that PBSAC is a much better catalyst in the catalytic reduction of Co(NH₃) $_{6}^{3+}$ than palm shell activated carbon (PSAC). The Co(NH₃) $_{6}^{3+}$ reduction reaction rate increases with PBSAC when the PBSAC dose is below 7.5 g/L. The Co(NH₃) $_{6}^{3+}$ reduction rate increases with its initial concentration. Best Co(NH₃) $_{6}^{3+}$ conversion is gained at a pH range of 2.0–6.0. A high temperature is favorable to such reaction. The intrinsic activation energy of 51.00 kJ/mol for the Co(NH₃) $_{6}^{3+}$ reduction catalyzed by PBSAC has been obtained. The experiments manifest that the simultaneous elimination of NO and SO₂ by the hexaminecobalt solution coupled with catalytic regeneration of hexaminecobalt(II) can maintain a NO removal efficiency of 90% for a long time.