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    Ionic Liquids as Surfactants in Aqueous Multiphase Systems for the Pd‐Catalyzed Hydrocarboxylation  

    New search for: Weber, Ariane
    New search for: Isbrücker, Philipp
    New search for: Schmidt, Marcel
    New search for: Schomäcker, Reinhard

    The suitability of ionic liquids (alkylmethylimidazolium bromides) as surfactants in an aqueous multiphase system for the Pd‐catalyzed hydrocarboxylation of 1‐dodecene is discussed. Attention is paid to the influence of these ionic liquids on the reaction performance and the phase separation. All tested ionic liquids are suitable as surfactants, but their concentration has a strong impact on the reaction performance. The resulting product concentrations are crucial for the phase behavior and so for the phase separation. In recycling experiments, the Pd‐catalyst is successfully separated and reused.

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    Ionic Liquids as Surfactants in Aqueous Multiphase Systems for the Pd‐Catalyzed Hydrocarboxylation  

    New search for: Weber, Ariane
    New search for: Isbrücker, Philipp
    New search for: Schmidt, Marcel
    New search for: Schomäcker, Reinhard

    The suitability of ionic liquids (alkylmethylimidazolium bromides) as surfactants in an aqueous multiphase system for the Pd‐catalyzed hydrocarboxylation of 1‐dodecene is discussed. Attention is paid to the influence of these ionic liquids on the reaction performance and the phase separation. All tested ionic liquids are suitable as surfactants, but their concentration has a strong impact on the reaction performance. The resulting product concentrations are crucial for the phase behavior and so for the phase separation. In recycling experiments, the Pd‐catalyst is successfully separated and reused.

    Access

    Check access
    Check availability in my library
    Order at Subito €

    Ionic Liquids as Surfactants in Aqueous Multiphase Systems for the Pd‐Catalyzed Hydrocarboxylation  

    New search for: Weber, Ariane
    New search for: Isbrücker, Philipp
    New search for: Schmidt, Marcel
    New search for: Schomäcker, Reinhard

    The suitability of ionic liquids (alkylmethylimidazolium bromides) as surfactants in an aqueous multiphase system for the Pd‐catalyzed hydrocarboxylation of 1‐dodecene is discussed. Attention is paid to the influence of these ionic liquids on the reaction performance and the phase separation. All tested ionic liquids are suitable as surfactants, but their concentration has a strong impact on the reaction performance. The resulting product concentrations are crucial for the phase behavior and so for the phase separation. In recycling experiments, the Pd‐catalyst is successfully separated and reused.

    Access

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    Check availability in my library
    Order at Subito €

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    Title:

    Ionic Liquids as Surfactants in Aqueous Multiphase Systems for the Pd‐Catalyzed Hydrocarboxylation  

    Contributors:

    Weber, Ariane (author) / Isbrücker, Philipp (author) / Schmidt, Marcel (author) / Schomäcker, Reinhard (author)

    Published in:

    Chemie Ingenieur Technik ; 93 ; 201-207

    Publication date:

    2021-01-01

    Size:

    7 pages

    ISSN:

    0009-286X , 1522-2640

    DOI:

    https://doi.org/10.1002/cite.202000165

    Type of media:

    Article (Journal)

    Type of material:

    Electronic Resource

    Language:

    English

    Keywords:

    Ionic liquids , Multiphase systems , Homogeneous catalysis , Catalyst recycling

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